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The application relates to a method for synthesizing DMF by electro-reducing carbon dioxide and dimethylamine, and belongs to the technical field of green organic synthesis. x The application relates to a method for synthesizing DMF by electro-reducing carbon dioxide and dimethylamine, and belongs to the technical field of green organic synthesis. The catalyst is used for the electro-catalytic C-N coupling reaction of dimethylamine and carbon dioxide, and DMF is efficiently synthesized under mild conditions. The catalyst has the advantages of rich active sites, high mass transfer efficiency and good stability, does not need to use a noble metal catalyst, and has the characteristics of low cost, environmental friendliness and easy scale production.