Composite flooding system containing lipopeptide biological surfactant and application thereof

A bio-surface, composite flooding technology, applied in the fields of fluid production, drilling composition, wellbore/well components, etc., can solve problems such as affecting large-scale applications, difficult field application control, and reducing polymer viscoelasticity. , to achieve the effect of promoting large-scale industrial application, easy control and application, and strengthening interface activity

Inactive Publication Date: 2011-08-17
EAST CHINA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] 1) The cost of chemically synthesized surfactants is high and the supply is in short supply, which affects the large-scale application;
[0006] 2) Chemically synthesized surfactants are difficult to degrade in nature, causing environmental pollution;
[0007] 3) Alkali can cause formation clay to disperse and migrate, resulting in a decrease in formation permeability; it reacts with oil layer fluid and rock minerals to form alkali scale, which will cause damage to the formation, and wellbore scaling will seriously affect the normal production of oil wells;
[0008] 4) The application of high-concentration alkali can cause serious corrosion of oil production equipment;
[0009] 5) Alkali will greatly reduce the viscoelasticity of the polymer and affect the oil displacement effect of the polymer;
[0010] 6) For the environment with high formation water salinity, the active range of the existing system is narrow, and the field application control is difficult

Method used

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  • Composite flooding system containing lipopeptide biological surfactant and application thereof
  • Composite flooding system containing lipopeptide biological surfactant and application thereof
  • Composite flooding system containing lipopeptide biological surfactant and application thereof

Examples

Experimental program
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Effect test

preparation example Construction

[0024] Preparation of lipopeptide biosurfactant:

[0025] The lipopeptide biosurfactant is produced by culture and fermentation of Bacillus subtilis (preservation number CGMCC1.1470) at 30°C. The culture medium was prepared with clean water, and its composition is shown in Table 1.

[0026] Table 1 prepares the medium composition of lipopeptide biosurfactant

[0027]

[0028] The lipopeptide biosurfactant content in the fermentation broth is 80-150mg / L.

Embodiment 1

[0029] Example 1 Composite oil displacement system under different lipopeptide biosurfactant concentrations

[0030] Lipopeptide biosurfactant: 0, 12~60mg / L

[0031] Heavy alkylbenzene sulfonate: 0.05%, w / v%

[0032] NaOH: 1.2%, w / v%

[0033] Prepare with water.

[0034] As can be seen from Table 2, under the conditions of NaOH: 1.2% (w / v%), heavy alkylbenzenesulfonate 0.05% (w / v%), the existing system (lipopeptide biosurfactant concentration is 0mg / L, NaOH: 1.2%w / v%, heavy alkyl benzene sulfonate 0.05w / v%) and crude oil interfacial tension is 0.037mN / m; add 12~60mg / L lipopeptide biosurfactant The inventive system can further reduce the interfacial tension and reach the ultra-low interfacial tension (10 -3 mN / m), the interfacial tension between the composite flooding system and crude oil with the best interfacial activity can even reach 10 ~4 mN / m, which is 2 orders of magnitude lower than that without lipopeptide biosurfactant.

[0035] Table 2 Interfacial activity of ...

Embodiment 2

[0037] Example 2 Interfacial activity of different composite flooding systems

[0038] Lipopeptide biosurfactant: 0, 12~60mg / L

[0039] Heavy alkylbenzene sulfonate: 0.01~0.15, w / v%

[0040] NaOH: 1.2, w / v%

[0041] Formation water preparation

[0042] As can be seen from Table 3, the existing lipopeptide biosurfactant concentration of 0 mg / L, NaOH 1.2w / v%, and heavy alkylbenzene sulfonate concentrations of 0.01, 0.03, and 0.05w / v% respectively The interfacial tension between the system and crude oil is 0.044, 0.037, 0.037mN / m respectively; the system of the present invention (containing lipopeptide biosurfactant) can further reduce the interfacial tension, and only a small amount of lipopeptide biosurfactant, heavy alkyl benzene sulfonate The ultra-low interfacial tension (10 -3 mN / m), and when the heavy alkylbenzene sulfonate concentration is 0.05%, the interfacial tension can be stabilized at 10 ~3 mN / m. However, to achieve the same interfacial tension value using the...

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Abstract

The invention provides a composite flooding system containing a lipopeptide biological surfactant. The composite flooding system comprises the following components: 6 to 120 mg/L of lipopeptide biological surfactant, 0.01 to 0.30 w/v percent of heavy alkylbenzene sulfonate, and 0.5 to 5 w/v percent of alkali. The lipopeptide biological surfactant is introduced into the conventional composite system, so that the consumption of the alkali and the heavy alkylbenzene sulfonate is obviously reduced, the interfacial activity of the system is further enhanced at the same time, the activity range of the system is further enlarged, and the system is controlled and applied more easily.

Description

technical field [0001] The invention relates to an oil field development oil displacement system, in particular to a composite oil displacement system composed of a lipopeptide biosurfactant, a heavy alkylbenzenesulfonate surfactant and an alkali. Background technique [0002] As a strategic resource, oil is of self-evident significance to every country. With the depletion of crude oil resources and the aggravation of the contradiction between crude oil demand, the technical demand for in-depth development of oil reservoirs is increasing day by day. In the initial stage of oil exploitation, the use of natural energy in the formation is called primary oil recovery; after the natural energy is exhausted, the recovery of energy by injecting water and gas into the oil reservoir is called secondary oil recovery. It is generally believed that after primary and secondary oil recovery, about 70% of the crude oil remains in the formation. The development of this part of crude oil b...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/584E21B43/22
Inventor 牟伯中杨世忠刘金峰秦慧
Owner EAST CHINA UNIV OF SCI & TECH
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