Preparation method and product of stable chlorine dioxide

A chlorine dioxide, stability technology, applied in a new generation of sterilization, preservative - chlorine dioxide, disinfection, stable chlorine dioxide field, can solve the problems of short stability period, easy decomposition and deactivation, affecting application, etc. Achieve the effects of good stability, excellent sustained-release performance, and widened application range

Inactive Publication Date: 2012-03-28
GUIZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the stable chlorine dioxide solution prepared by the above-mentioned absorption liquid has been applied in many industries, there are also some problems. Because the stability of multiple chlorine dioxide needs to be added in the preparation process, the product is in some fields. For example, the use in the food industry is limited, and at the same time, such stable chlorine dioxide solutions usually have short stability periods and are easily decomposed and deactivated, which also affect their application in some fields.

Method used

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  • Preparation method and product of stable chlorine dioxide
  • Preparation method and product of stable chlorine dioxide
  • Preparation method and product of stable chlorine dioxide

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Embodiment 1: 47.5g sodium phosphate (Na 3 PO 4 ) was dissolved in 490ml of aqueous solution, adding 22ml of concentration by weight was 30% hydrogen peroxide (H 2 o 2 ), after shaking evenly, absorb chlorine dioxide as the absorption liquid, stop the absorption after the absorption liquid turns light yellow, adjust the pH value of the absorption liquid to 6.5-7.0 with sodium phosphate, and store the absorption liquid in a brown bottle. The chlorine dioxide content in the sample is 2.41%

Embodiment 2

[0030] Embodiment 2: 100g sodium phosphate (Na 3 PO 4 ) was dissolved in 500ml aqueous solution at 30°C, adding 50ml weight percent concentration was 30% hydrogen peroxide (H 2 o 2 ), after shaking evenly, absorb chlorine dioxide as the absorption liquid, stop the absorption after the absorption liquid turns light yellow, adjust the pH value of the absorption liquid to 6.5-7.0 with sodium phosphate, and store the absorption liquid in a brown bottle. The chlorine dioxide content in the sample is 5.04%

Embodiment 3

[0031] Embodiment 3: 20.0g sodium phosphate (Na 3 PO 4 ) was dissolved in 490ml aqueous solution, adding 10ml weight percent concentration was 30% hydrogen peroxide (H 2 o 2), after shaking evenly, absorb chlorine dioxide as the absorption liquid, stop the absorption after the absorption liquid turns light yellow, adjust the pH value of the absorption liquid to 6.5-7.0 with sodium phosphate, and store the absorption liquid in a brown bottle. The chlorine dioxide content in the sample was 1.02%.

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Abstract

The invention discloses a preparation method of stable chlorine dioxide. The chlorine dioxide gas can be used to prepare stable chlorine dioxide which has good stability and can be stored for long term. Sodium phosphate and hydrogen peroxide are used as basic components for stabilizing chlorine dioxide, and can have self-stabilization function in the absorption process and efficiently absorb chlorine dioxide to form a stable chlorine dioxide solution. The prepared product has the following advantages: the content of active chlorine dioxide is high, the stability is good, the production cost is low, the operations are convenient, other stabilizers are not required to be added in production, the storage stability is good, the product is safe in use and the like. When in use, an acid activator is added in the product to generate chlorine dioxide gas. The prepared stable chlorine dioxide has good slow release property; and according to the type and concentration of the used acid activator, the slow release of the product can be easily controlled, chlorine dioxide can be released thoroughly and the utilization rate is high. The product can be widely used in the disinfection, sterilization, preservation, deodorizing and the like of various industries.

Description

Technical field: [0001] The invention belongs to the field of a new generation of sterilization, disinfection and antistaling agent-chlorine dioxide and stable chlorine dioxide. The invention can prepare the chlorine dioxide gas into a stable chlorine dioxide solution with good stability and long-term storage. Background technique: [0002] The preparation of stable chlorine dioxide solution is usually made by absorbing chlorine dioxide gas with a stable solution prepared by sodium percarbonate, sodium perborate, sodium carbonate and hydrogen peroxide. Although the stable chlorine dioxide solution prepared by the above-mentioned absorption liquid has been applied in many industries, there are also some problems. Because the stability of multiple chlorine dioxide needs to be added in the preparation process, the product is in some fields. For example, the use in the food industry is limited, and at the same time, such stable chlorine dioxide solutions usually have short stab...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B11/02
Inventor 谢承卫高弦黄晓丹
Owner GUIZHOU UNIV
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