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Preparation method of tourmaline/magnetic chitosan microsphere treatment agent

A technology of chitosan microspheres and treatment agents, applied in water/sewage treatment, chemical instruments and methods, adsorption water/sewage treatment, etc., can solve problems such as water purification by water purifiers that have not yet been seen, and achieve remarkable treatment effects , low cost, strong repeatable effect

Inactive Publication Date: 2014-09-10
CHONGQING UNIV OF ARTS & SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

So far, there have been no relevant reports on the use of chitosan and tourmaline to jointly prepare water purifiers for water purification

Method used

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  • Preparation method of tourmaline/magnetic chitosan microsphere treatment agent
  • Preparation method of tourmaline/magnetic chitosan microsphere treatment agent
  • Preparation method of tourmaline/magnetic chitosan microsphere treatment agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A water treatment agent is prepared in the following steps:

[0027] a. Pretreatment of tourmaline

[0028] Crush tourmaline through a 200-mesh sieve, wash 5-7 times with NaOH solution with a mass concentration of 5% to remove the anions and cations attached to the surface, and then wash with deionized water for the same number of times, then put it in an oven to dry, and wait for use;

[0029] b. Preparation of superparamagnetic Fe3O4 powder

[0030] Weigh 5.56g FeSO 4 ·7H 2 O, 6.5g FeCl 3 and 1.7mL of concentrated hydrochloric acid were dissolved in 50mL of N 2Degas the distilled water, then add the above dropwise to 250mL of 1.0mol / L NaOH solution; stir in a water bath at 80°C at a slow speed (100r / min) for 5min, then stir mechanically at a rapid speed (2000r / min), and wait for the solution A black precipitate appeared in the solution, and the stirring was continued for 30 minutes; after the reaction was completed, it was left to cool down to room temperature, ...

Embodiment 2～7

[0035] Embodiment 2~7: carry out by following each material and step, all the other are with embodiment 1.

[0036]

[0037]

[0038] The removal rate of the tourmaline / magnetic chitosan microspheres prepared above is 78% to 90% for the volatile phenol in the source water.

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Abstract

The invention provides a preparation method of a tourmaline / magnetic chitosan microsphere treatment agent which is prepared by dissolving and uniformly mixing mixed powder of tourmaline and magnetic chitosan microspheres in sodium alginate and polyvinyl alcohol, and solidifying and balling. The magnetic chitosan microsphere is prepared by using superparamagnetic ferroferric oxide, 1 to 10 weight percent of chitosan acetic acid liquid, liquid paraffin, Span-80 and glutaraldehyde as reaction materials through an emulsion crosslinking method, wherein the mass ratio of the superparamagnetic ferroferric oxide to the chitosan acetic acid liquid is 1:(1-10), the volume ratio of the liquid paraffin to the Span-80 is (10-100):1, the volume ratio of the chitosan acetic acid liquid of superparamagnetic ferroferric oxide to mixed liquid of paraffin-Span-80 is 1:(1-10), and the volume ratio of the mixed liquid of superparaferroferric oxide, paraffin and Span-80 to glutaraldehyde is (5-50):1. According to the water treating agent, the removal rate of volatile phenol in water is between 80 and 90 percent, the removal rate of chromium in water is 93 percent; and the magnetic chitosan microsphere treating agent has the advantages of large adsorption capacity, high purification efficiency, low cost, regeneration, no toxicity, no pollution to environment and the like.

Description

[0001] The present invention is a divisional application with an application date of September 23, 2011 and an application number of 201110284933.4. technical field [0002] The invention relates to a water treatment preparation, in particular to a water treatment agent with good effect on removing volatile phenol in water and a preparation method thereof, belonging to the field of water treatment. Background technique [0003] In recent years, the unique properties and structure of magnetic chitosan microspheres have attracted widespread attention, especially in the application research of water treatment, which has achieved good results. Magnetic chitosan can be used to remove Cu from water 2+ 、Cr 2+ , Hg 2+ , Zn 2+ , Pb 2+ , Ca 2+ 、Ag + And other metal ions, can also be used to treat organic wastewater, and can quickly reach equilibrium. Wong and G. Mckay et al. [22-23] Chitosan has done a detailed study on the treatment of printing and dyeing wastewater. The resu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/26B01J20/30C02F1/28C02F1/58C02F1/62
Inventor 朱启红夏红霞
Owner CHONGQING UNIV OF ARTS & SCI
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