Environment-friendly salt-resistant high-temperature-resistant oil displacement agent containing biological surfactant and used in petrochemical industry

A petrochemical and surfactant technology, applied in chemical recovery, drilling compositions, chemical instruments and methods, etc., can solve the problem that the oil displacement agent cannot be degraded, the amount of use is large, and the oil displacement agent cannot be effectively and reliably exploited To achieve the effect of improving oil displacement efficiency and sweep coefficient, reducing raw material cost, and avoiding secondary pollution

Active Publication Date: 2015-04-22
SHANDONG XINGANG CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Petroleum is an important energy resource in production and life. With the continuous exploitation of petroleum, most oil fields have entered a period of high water content, low permeability, heavy oil, high temperature, and high salinity. Most of the remaining oil reservoirs are distributed in extremely heterogeneous carbonate In places where mining is difficult such as fractured caves, it is impossible to use traditional oil displacement agents for effective and reliable mining.
Although some scholars have developed a series of new surfactants for oil extraction, there are still problems such as a large amount of use and the inability of the oil displacement agent to degrade.

Method used

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  • Environment-friendly salt-resistant high-temperature-resistant oil displacement agent containing biological surfactant and used in petrochemical industry
  • Environment-friendly salt-resistant high-temperature-resistant oil displacement agent containing biological surfactant and used in petrochemical industry

Examples

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Embodiment 1

[0029] Heat the tea saponin mother liquor extracted from tea dregs and trimethylolpropane to 90-95°C in a mixing reactor, react under the catalysis of cerium sulfate, recover the catalyst after the reaction is complete, and concentrate to obtain tea soap Plain modifier, wherein tea saponin and trimethylol propane carry out mixing reaction according to the molar ratio of 3.5:1.

Embodiment 2

[0031] Mix and react the tea saponin mother liquor and thionyl chloride in a mixing reactor at a reaction temperature of 20-25°C, wherein the tea saponin and thionyl chloride are mixed and reacted at a molar ratio of 1.1:1; After the end, add trimethylolpropane and carry out mixed reaction at 40-45°C. The amount of trimethylolpropane added is 1 / 3 of that of thionyl chloride. After the reaction is complete, concentrate to obtain the tea saponin modifier.

Embodiment 3

[0033] Heat the tea saponin mother liquor extracted from tea dregs and trimethylolpropane to 90-95°C in a mixing reactor, and react under the catalysis of activated carbon-supported p-toluenesulfonic acid catalyst, and recover the catalyst after the reaction is complete After concentration, the tea saponin modifier is obtained, wherein the tea saponin and trimethylolpropane are mixed and reacted according to the molar ratio of 3.5:1.

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Abstract

The invention discloses an environment-friendly salt-resistant high-temperature-resistant oil displacement agent containing biological surfactant and used in the petrochemical industry. The oil displacement agent comprises, by weight, 0.1 to 1.2 parts of sodium surfactin, 5 to 8 parts of tea saponin modifier and 80 to 85 parts of water. According to the invention, the sodium surfactin, the tea saponin modifier and other auxiliary components are combined for preparation of the oil displacement agent; the oil displacement agent can be used for exploitation of high-water-content, low-permeability, thickened, high-temperature and high-salt oil reservoirs and can improve oil displacement efficiency, sweep efficiency and recovery efficiency; the tea saponin modifier is prepared from tea saponin extracted from tea seed meal, so cost for the raw materials of the oil displacement agent is reduced; moreover, because of the characteristics of the sodium surfactin and the tea saponin, the sodium surfactin can be decomposed into 4 single amino acids and the tea saponin can be naturally decomposed by microorganisms after demulsification of crude oil; and the separated oil displacement has excellent degradation performance, so secondary pollution caused by incapable degradation of the separated oil displacement is avoided and environmental protection effects are obtained.

Description

technical field [0001] The invention relates to the field of oil exploitation, in particular to an environment-friendly salt-resistant and high-temperature oil-displacement agent containing biosurfactant for petrochemical industry. Background technique [0002] Petroleum is an important energy resource in production and life. With the continuous exploitation of petroleum, most oil fields have entered a period of high water content, low permeability, heavy oil, high temperature, and high salinity. Most of the remaining oil reservoirs are distributed in extremely heterogeneous carbonate In places where mining is difficult such as fractured caves, effective and reliable mining cannot be carried out using traditional oil displacement agents. Although some scholars have developed a series of new surfactants for oil extraction, there are still problems such as large usage and inability to degrade oil displacement agents. Contents of the invention [0003] The object of the pres...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/584E21B43/22
CPCY02P20/584C09K8/584
Inventor 程叶红
Owner SHANDONG XINGANG CHEM
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