A method for combined removal of organic matter in water by potassium permanganate-biological manganese oxidation

A potassium permanganate and manganese oxidation technology, applied in the field of water treatment, can solve the problems of chroma pollution, secondary pollution of water body, etc., and achieve the effect of simple operation

Active Publication Date: 2020-06-30
RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, potassium permanganate pre-oxidation is prone to chromatic pollution, and when it oxidizes organic pollutants, it will produce soluble Mn 2+ ’ Secondary pollution to water bodies

Method used

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  • A method for combined removal of organic matter in water by potassium permanganate-biological manganese oxidation
  • A method for combined removal of organic matter in water by potassium permanganate-biological manganese oxidation
  • A method for combined removal of organic matter in water by potassium permanganate-biological manganese oxidation

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Embodiment 1. Potassium permanganate-biological manganese oxide oxidation combined treatment of wastewater containing Tyr, BP-4 organic pollutants

[0035] Before industrial application, first verify the method of the present invention to Mn 2+ , Tyr, BP-4 removal effect.

[0036] 1. Potassium permanganate pre-oxidation

[0037] An aqueous solution containing 176 mg / L Tyr and 1 mg / L BP-4 was prepared to completely dissolve each component. Add 153.6 mg / L potassium permanganate, and then let stand for 20 minutes.

[0038] In the reaction process described in step 1, get the described reaction solution at a specified time interval respectively, measure potassium permanganate and be the absorbance at wavelength of 525nm, and the detection method is as follows:

[0039] Potassium permanganate absorbance: use Shimadzu U-3010 UV-Vis spectrophotometer to detect the absorbance of the reaction solution at a wavelength of 525nm;

[0040] Due to the rapidity of the reaction bet...

Embodiment 2

[0058] Example 2. Oxidation of BP-4 by biological manganese oxide

[0059] 1. Preparation of biological manganese oxide

[0060] PYG medium (peptone, glucose, yeast extract 0.25g / L each, CaCl 2 .2H 2 O content 8mg / L, MgSO 4 .7H 2 O content 0.5g / L, MnCl 2 Content 5mg / L, add deionized water to 1L) to activate Pseudomonas putida QJX-1, and the buffer in the medium is HEPES with a final concentration of 10-20mM, pH7.5. Among them, HEPES buffer was filtered and sterilized with a 0.22 μm filter membrane. In the same batch, a total of 5 L of culture solution was prepared, and then the culture solution was shaken at 30 °C and 170 rpm for 72 h.

[0061] After culturing, the bacterial liquid was placed in a centrifuge at 7500 r min. -1 Centrifuge for 5 minutes. Pour off the supernatant and collect the biological manganese oxide. The biological manganese oxide precipitate was placed in a -20°C refrigerator for 24 hours, and finally put into a freeze dryer for drying for 48 hours ...

Embodiment 3

[0070] Embodiment 3: a kind of method of potassium permanganate preoxidation-biological manganese oxidation combined removal of organic matter in water

[0071] Using the method of the present invention to remove organic matter in surface water, before treatment, the concentration of Tyr in the water to be treated is 25 μg / L, and the concentration of BP-4 is 38 μg / L;

[0072] (1) Potassium permanganate preoxidation

[0073] Add potassium permanganate to the water to be treated, the concentration of potassium permanganate is 0.5mg / L, the water to be treated is pre-oxidized for 5 minutes to obtain pre-oxidized water, and the concentration of Tyr in the sewage is reduced from 25 μg / L to 12 μg / L, and produce 0.07mg / L soluble Mn 2+ ;

[0074] (2) Membrane formation in biological filter and domestication of manganese-oxidizing bacteria

[0075] ①Put the water to be treated into the inlet pipe of the biological aerated filter device and circulate it to the surface of the packing i...

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Abstract

The invention belongs to the technical field of water treatment and in particular relates to a method for removing natural and artificially synthesized organic matters in water with combination of potassium permanganate-biological manganese oxidation. The method comprises the following steps: firstly, performing preoxidation on raw water with pollutants by potassium permanganate, and putting a manganese-oxidizing microorganism of which the preservation number is CGMCC No.6630 into a residual liquid which is subjected to preoxidation with potassium permanganate and comprises tyrosine and BP-4. Therefore, Tyr is utilized, soluble Mn<2+> is converted into insoluble Mn<4+> oxides, and with the combination of the Mn<4+> oxides, manganese oxidation bacteria and the generated biological manganese oxide, trace pollutants BP-4 can be effectively oxidized and adsorbed; the operation is simple, and natural and artificially synthesized organic matters such as soluble Mn<2+>, manganese oxide and BP-4 can be effectively removed at one step.

Description

Technical field: [0001] The invention belongs to the technical field of water treatment, and in particular relates to an application of potassium permanganate-biological manganese oxidation combined to remove natural and artificially synthesized organic matter in water. Background technique: [0002] The composition of natural water is relatively complex, which contains a variety of natural organic matter and synthetic organic matter. Tyr is an aromatic natural amino acid with a simple structure that exists in a variety of polypeptides, proteins, and algae. In the detection of influent water of sewage treatment plant, the highest content of Tyr can reach 27.4μg / L, which is a representative substance of natural organic matter. BP-4 is a commonly used benzophenone UV sunscreen agent, which has a large production volume and a wide range of applications. With the extensive use of humans, a large amount of it enters the natural water body, which will pose a potential threat to e...

Claims

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Application Information

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Patent Type & AuthorityPatents(China)
IPC IPC(8): C02F9/14C02F101/20
CPCC02F1/72C02F3/34C02F2101/206C02F2305/06
Inventor柏耀辉菅之舆常洋洋刘锐平曲久辉
OwnerRES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI