A kind of copolymerization method of ethylene and terminal alkenyl silane/siloxane
A technology of terminal alkenyl silane and siloxane, applied in the field of copolymerization of ethylene and terminal alkenyl silane/siloxane, which can solve the problems of low polymerization activity, low polymer molecular weight and branching degree, and high price
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment approach
[0026] According to a preferred embodiment of the present invention, the main catalyst is selected from at least one of the following complexes,
[0027] Complex 1: R 1 = R 3 = R 4 = R 6 = Me,R 2 = R 5 = H, X = Br;
[0028] Complex 2: R 1 = R 3 = R 4 = R 6 =Et,R 2 = R 5 = H, X = Br;
[0029] Complex 3: R 1 = R 3 = R 4 = R 6 =iPr, R 2 = R 5 = H, X = Br;
[0030] Complex 4: R 1 = R 2 = R 3 = R 4 = R 5 = R 6 =Me, X=Br;
[0031] Complex 5: R 1 = R 3 = R 4 = R 6 = Me,R 2 = R 5 =Br, X=Br;
[0032] Complex 6: R 1 = R 3 = R 4 = R 6 = Me,R 2 = R 5 = Et, X = Br;
[0033] Complex 7: R 1 = R 3 = R 4 = R 6 =Et,R 2 = R 5 =Me, X=Br;
[0034] Complex 8: R 1 = R 3 = R 4 = R 6 =Et,R 2 = R 5 =Br, X=Br;
[0035] Complex 9: R 1 = R 3 = R 4 = R 6 = F, R 2 = R 5 = H, X = Br;
[0036] Complex 10: R 1 = R 3 = R 4 = R 6 = Cl, R 2 = R 5 = H, X = Br;
[0037] Complex 11: R 1 = R 3 = R 4 = R 6 =Br,R 2 = R 5 = H, X = Br;
[0038] Compl...
Embodiment 1
[0085] The 1L stainless steel polymerization kettle equipped with mechanical stirring was continuously dried at 130°C for 6hrs, vacuumized while hot and heated with N 2 Gas replacement 3 times; add 6.5 mg (10 μmol) of complex 2, then evacuate and replace 3 times with ethylene, inject 500 mL of toluene, add 6.5 mL of methylaluminoxane (MAO) (1.53 mol / L toluene solution) , make Al / Ni=1000, 5mL of allyltrimethoxysilane (28.7mmol), at 60°C, keep ethylene pressure of 10atm, and stir for 30min. Finally, it was neutralized with an ethanol solution acidified with 5 volume % hydrochloric acid to obtain a polymer. The polymerization activity and performance parameters of the polymer are shown in Table 1.
Embodiment 2
[0087] The 1L stainless steel polymerization kettle equipped with mechanical stirring was continuously dried at 130°C for 6hrs, vacuumized while hot and heated with N 2 Gas replacement 3 times; add 6.5 mg (10 μmol) of complex 2, then vacuumize and replace with ethylene for 3 times, inject 500 mL of toluene, and then add 6.5 mL of methylaluminoxane (MAO) (1.53 mol / L toluene solution) , make Al / Ni=1000, 8mL of allyltrimethoxysilane (45.9mmol), at 60°C, keep 10atm of ethylene pressure, and stir for 30min. Finally, it was neutralized with an ethanol solution acidified with 5 volume % hydrochloric acid to obtain a polymer. The polymerization activity and performance parameters of the polymer are shown in Table 1.
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com