Reactive dye for turquoise blue printing based on copper phthalocyanine color body and preparation method and application thereof
A technology of reactive dyes and copper phthalocyanine, applied in reactive dyes, azo dyes, organic dyes, etc., can solve the problems of affecting color fastness, poor color reproducibility of printed and dyed fabrics, large cylinder difference, etc., and achieve good levelness. , excellent washing ability, simple preparation process effect
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Embodiment 1
[0033] The synthetic technique of the emerald blue reactive dye of following structure:
[0034]
[0035] (1) Preparation of copper phthalocyanine sulfonyl chloride: at room temperature, add 80 mL of chlorosulfonic acid to a three-necked flask equipped with a reflux condenser and a tail gas absorption device, add 15 g of copper phthalocyanine under stirring, and then heat up to 135 ° C for reaction 5h, then lower the temperature to 60°C, add 22mL of thionyl chloride to it, raise the temperature to 100°C for 2h, then lower the temperature to below 30°C, slowly add the system to ice water while stirring, suction filter, filter the cake with an appropriate amount of ice Wash with water to obtain 58 g of copper phthalocyaninesulfonyl chloride filter cake.
[0036] (2) Preparation of copper phthalocyanine turquoise blue base: the copper phthalocyanine sulfonyl chloride in step (1) was beaten for 1 h in an ice-water bath. Accurately weigh 5.04g of 2,4-diaminobenzenesulfonic acid...
Embodiment 2
[0041] The synthetic technique of the emerald blue reactive dye of following structure:
[0042]
[0043] (1) Preparation of copper phthalocyanine sulfonyl chloride: at room temperature, add 80 mL of chlorosulfonic acid to a three-necked flask equipped with a reflux condenser and a tail gas absorption device, add 15 g of copper phthalocyanine under stirring, and then heat up to 135 ° C for reaction 5h, then lower the temperature to 60°C, add 22mL of thionyl chloride to it, raise the temperature to 100°C for 2h, then lower the temperature to below 30°C, slowly add the system to ice water while stirring, suction filter, filter the cake with an appropriate amount of ice Wash with water to obtain 58 g of copper phthalocyaninesulfonyl chloride filter cake.
[0044] (2) Preparation of copper phthalocyanine turquoise blue base: the copper phthalocyanine sulfonyl chloride in step (1) was beaten for 1 h in an ice-water bath. Accurately weigh 5.04g of 2,4-diaminobenzenesulfonic acid...
Embodiment 3
[0049] The synthetic technique of the emerald blue reactive dye of following structure:
[0050]
[0051] (1) Preparation of copper phthalocyanine sulfonyl chloride: at room temperature, add 80 mL of chlorosulfonic acid to a three-necked flask equipped with a reflux condenser and a tail gas absorption device, add 15 g of copper phthalocyanine under stirring, and then heat up to 135 ° C for reaction 5h, then lower the temperature to 60°C, add 22mL of thionyl chloride to it, raise the temperature to 100°C for 2h, then lower the temperature to below 30°C, slowly add the system to ice water while stirring, suction filter, filter the cake with an appropriate amount of ice Wash with water to obtain 58 g of copper phthalocyaninesulfonyl chloride filter cake.
[0052] (2) Preparation of copper phthalocyanine turquoise blue base: the copper phthalocyanine sulfonyl chloride in step (1) was beaten for 1 h in an ice-water bath. Accurately weigh 5.04g of 2,4-diaminobenzenesulfonic acid...
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