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Reactive dye for turquoise blue printing based on copper phthalocyanine color body and preparation method and application thereof

A technology of reactive dyes and copper phthalocyanine, applied in reactive dyes, azo dyes, organic dyes, etc., can solve the problems of affecting color fastness, poor color reproducibility of printed and dyed fabrics, large cylinder difference, etc., and achieve good levelness. , excellent washing ability, simple preparation process effect

Active Publication Date: 2019-02-01
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, reactive turquoise blue dye is often used to mix bright green with reactive bright yellow dye. However, due to the different structure of the dyes in the process of blending green, the dyeing rate, lifting power, and color fixation rate of each dye are different, and printing and dyeing fabrics will appear The color reproducibility is poor, the vat difference is large, and the color fastness is affected. Therefore, it is very important to develop a single-structure light green reactive dye to improve the color reproducibility.

Method used

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  • Reactive dye for turquoise blue printing based on copper phthalocyanine color body and preparation method and application thereof
  • Reactive dye for turquoise blue printing based on copper phthalocyanine color body and preparation method and application thereof
  • Reactive dye for turquoise blue printing based on copper phthalocyanine color body and preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0033] The synthetic technique of the emerald blue reactive dye of following structure:

[0034]

[0035] (1) Preparation of copper phthalocyanine sulfonyl chloride: at room temperature, add 80 mL of chlorosulfonic acid to a three-necked flask equipped with a reflux condenser and a tail gas absorption device, add 15 g of copper phthalocyanine under stirring, and then heat up to 135 ° C for reaction 5h, then lower the temperature to 60°C, add 22mL of thionyl chloride to it, raise the temperature to 100°C for 2h, then lower the temperature to below 30°C, slowly add the system to ice water while stirring, suction filter, filter the cake with an appropriate amount of ice Wash with water to obtain 58 g of copper phthalocyaninesulfonyl chloride filter cake.

[0036] (2) Preparation of copper phthalocyanine turquoise blue base: the copper phthalocyanine sulfonyl chloride in step (1) was beaten for 1 h in an ice-water bath. Accurately weigh 5.04g of 2,4-diaminobenzenesulfonic acid...

Embodiment 2

[0041] The synthetic technique of the emerald blue reactive dye of following structure:

[0042]

[0043] (1) Preparation of copper phthalocyanine sulfonyl chloride: at room temperature, add 80 mL of chlorosulfonic acid to a three-necked flask equipped with a reflux condenser and a tail gas absorption device, add 15 g of copper phthalocyanine under stirring, and then heat up to 135 ° C for reaction 5h, then lower the temperature to 60°C, add 22mL of thionyl chloride to it, raise the temperature to 100°C for 2h, then lower the temperature to below 30°C, slowly add the system to ice water while stirring, suction filter, filter the cake with an appropriate amount of ice Wash with water to obtain 58 g of copper phthalocyaninesulfonyl chloride filter cake.

[0044] (2) Preparation of copper phthalocyanine turquoise blue base: the copper phthalocyanine sulfonyl chloride in step (1) was beaten for 1 h in an ice-water bath. Accurately weigh 5.04g of 2,4-diaminobenzenesulfonic acid...

Embodiment 3

[0049] The synthetic technique of the emerald blue reactive dye of following structure:

[0050]

[0051] (1) Preparation of copper phthalocyanine sulfonyl chloride: at room temperature, add 80 mL of chlorosulfonic acid to a three-necked flask equipped with a reflux condenser and a tail gas absorption device, add 15 g of copper phthalocyanine under stirring, and then heat up to 135 ° C for reaction 5h, then lower the temperature to 60°C, add 22mL of thionyl chloride to it, raise the temperature to 100°C for 2h, then lower the temperature to below 30°C, slowly add the system to ice water while stirring, suction filter, filter the cake with an appropriate amount of ice Wash with water to obtain 58 g of copper phthalocyaninesulfonyl chloride filter cake.

[0052] (2) Preparation of copper phthalocyanine turquoise blue base: the copper phthalocyanine sulfonyl chloride in step (1) was beaten for 1 h in an ice-water bath. Accurately weigh 5.04g of 2,4-diaminobenzenesulfonic acid...

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Abstract

The present invention relates to a reactive dye for a turquoise blue printing based on a copper phthalocyanine color body and a preparation method and an application thereof. The kind of the turquoiseblue reactive dye is obtained by chlorosulfonation of copper phthalocyanine, preparation of phthalocyanine turquoise blue base, primary condensation and secondary condensation. The obtained turquoiseblue reactive dye is suitable for printing on cotton, linen and other textiles, has an excellent easy water washing ability, good leveling property and excellent lifting power and dyeing depth, and has a higher fixation rate than that of commercial dyes, and printing textiles show relatively excellent color fastness to light and rubbing color fastness, and have a very good application prospect.

Description

technical field [0001] The invention belongs to the field of reactive dyes, in particular to a class of reactive dyes for emerald blue printing based on copper phthalocyanine chromophores and a preparation method and application thereof. Background technique [0002] Reactive dyes have developed rapidly because they can be combined with fibers by covalent bonds, have excellent wet fastness and level dyeing performance, bright colors, complete chromatograms, and low cost. Most of the light-colored varieties of reactive dyes such as yellow, orange, and red have an azo structure, and the purple, brown, and black varieties often use metal-complexed azo structures. Most of the bright blue colors are anthraquinone derivatives. The reactive turquoise blue dye whose parent is copper phthalocyanine has always occupied a very important position because of its unique turquoise blue color. At present, reactive turquoise blue dye is often used to mix bright green with reactive bright ye...

Claims

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Application Information

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IPC IPC(8): C09B62/04C09B62/503C09B67/02
CPCC09B62/046C09B62/503C09B67/0097
Inventor 谢孔良侯爱芹胡柳高爱芹张红娟
Owner DONGHUA UNIV
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