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Pinoxaden-containing herbicide composition and application thereof

A pinoxaden and herbicide technology, applied in the field of pinoxaden-containing herbicidal compositions, can solve the problems of common occurrence of resistance, prominent weed resistance, complex dissolution mechanism, etc., and achieve reliable thermal storage stability Guarantee, increase dissolution and dispersion effect, and obvious synergistic effect

Inactive Publication Date: 2020-12-18
NANTONG JIANGSHAN AGROCHEM & CHEM LIMITED LIABILITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, chemical methods of weeding have been carried out for a long time, and my country’s winter wheat faces three problems in weed control: First, the long-term use of weed control for broad-leaved weeds such as Benuron has resulted in dominant broad-leaved weeds in wheat fields (such as Artemisia sorenzo, shepherd’s purse, etc.) Resistance generally occurs; second, due to the single long-term use of herbicides against broad-leaved weeds, resulting in the double effect of weeds, some grass weeds and some difficult-to-control disasters, etc.) emerge in endlessly; third, herbicide damage occurs frequently
However, pinoxaden also has three major problems: first, it will cause phytotoxicity to wheat and barley seedlings; second, long-term single use will lead to outstanding weed resistance; third, it is easy to decompose
Due to the complexity of the solubilizing mechanism, many of the mechanisms are still unclear. Therefore, there is no clear rule to follow in the selection of the solubilizing agent. Generally, the water-soluble intermolecular complexes and complexes can only be selected according to the properties of the drug. Substances of salt or association

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] .

[0032] Dissolve herbicides (pinoxaden, clodinafop-propargyl) in the solvent of cyclohexanone and 150# mineral spirits, then add emulsifiers (500# and 600#), and finally add BHT and oxaclofenac. The above mixture was stirred until a clear liquid formed.

Embodiment 2

[0034] .

[0035] Dissolve herbicides (pinoxaden, florasulam) in tetrahydrofurfuryl acetate, 200# solvent naphtha, and DMF solvent, then add emulsifiers (500#, 600#, 1602), and finally add BHA , clofenacyl. The above mixture was stirred until a clear liquid formed.

Embodiment 3

[0037] .

[0038] Dissolve herbicides (pinoxaden, clodinafop-propargyl) in tetrahydrofuran, 200# solvent naphtha and ethylene glycol monomethyl ether solvent, then add emulsifiers (500#, 600#, 1602), and finally add 6- tert-butyl-4-methoxyphenyl ether, clofenacyl. The above mixture was stirred until a clear liquid formed.

[0039] The stability test results of 3 preparation examples are shown in Table 1 and Table 2:

[0040] Table 1

[0041] .

[0042] Note: Blank 1, Blank 2 and Blank 3 are emulsifiable concentrate systems without adding stabilizers BHT, BHA and 6-tert-butyl-4-methoxyphenyl ether in Embodiment 1, Embodiment 2, and Embodiment 3 respectively. The removed part of the stabilizer is replenished with solvent.

[0043] Table 2

[0044] .

[0045] It can be seen from Examples 1 to 3 that the products formulated by the invention are all qualified in terms of heat storage stability, cold storage stability and emulsion stability, and meet the quality standar...

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PUM

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Abstract

The invention relates to a pinoxaden-containing herbicide composition, which comprises the following components in percentage by mass: 0.5%-10% of pinoxaden, 0.5%-10% of clodinafop-propargyl or florasulam, 5%-20% of a cosolvent, 20%-87.9% of a solvent, 5%-20% of an emulsifier, 0.1%-5% of a stabilizer and 0.5%-20% of a safener. According to application requirements, several components are compounded and processed into an emulsifiable concentrate product, the synergistic interaction is obvious, and the usage amount is obviously reduced. Meanwhile, by screening and adding a cosolvent with higherboiling point and capable of forming effective complexation and the solvent, the solubility and the heat stability are improved, and the defect that pinoxaden in a product system is easy to decomposeis overcome.

Description

technical field [0001] The invention belongs to the technical field of pesticides and relates to a herbicidal composition containing pinoxaden. Background technique [0002] Wheat is the most important food crop in northern my country, with an annual planting area of ​​25 million hectares nationwide. In recent years, with rising prices, the planting area has increased. Chemical weeding has become one of the main means of controlling weeds in wheat fields in agriculture. [0003] However, chemical methods of weeding have been carried out for a long time, and my country’s winter wheat faces three problems in weed control: First, the long-term use of weed control for broad-leaved weeds such as Benuron has resulted in dominant broad-leaved weeds in wheat fields (such as Artemisia sorenzo, shepherd’s purse, etc.) Resistance generally occurs; second, due to the single long-term use of herbicides against broad-leaved weeds, resulting in the double effect of weeds, some grass weeds ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N43/90A01N43/40A01N25/04A01N25/22A01N25/32A01P13/00
CPCA01N43/90A01N43/40A01N25/22A01N25/32A01N25/30A01N25/02
Inventor 任新峰许映蓉魏伟李璟
Owner NANTONG JIANGSHAN AGROCHEM & CHEM LIMITED LIABILITY
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