The invention relates to the technical field of oral care compositions, in particular to an oral care composition and a preparation method and application thereof.The oral care composition comprises a first composition and a second composition, the first composition comprises an anti-sensitive agent, a cosolvent, a first
thickening agent, a surfactant and a first auxiliary, and the second composition comprises an anti-sensitive agent, a cosolvent, a second
thickening agent, a surfactant and a second auxiliary; the first composition comprises
phthalimide peroxyhexanoic acid, a cosolvent, a first
thickening agent, a first auxiliary agent and deionized water, the second composition comprises
phthalimide peroxyhexanoic acid, a cosolvent, a second thickening agent, a second auxiliary agent and deionized water, at least one of the cosolvent, the first auxiliary agent and the second auxiliary agent contains a flavoring agent, and the first composition and the second composition are separately stored before use. The anti-sensitive agent is prevented from being in contact with the
phthalimide peroxyhexanoic acid before use. According to the invention, the first composition and the second composition are respectively and independently stored, so that natural
decomposition and activity attenuation of phthalimide peroxycaproic acid in the
shelf life of the product are inhibited, and the product is ensured to retain high effective
active oxygen content after being stored for a long time.