Acridinyl complex crystal, doped crystal luminescent material and preparation method and application of acridinyl complex crystal and doped crystal luminescent material

A technology of luminescent materials and complexes, applied in luminescent materials, cadmium organic compounds, chemical instruments and methods, etc., can solve the problems that affect the wide application of light-emitting devices, poor thermal/optical stability, and low crystallinity

Pending Publication Date: 2022-03-08
LUOYANG NORMAL UNIV
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Problems solved by technology

However, organic light-emitting functional materials have poor thermal/optical stabili...

Method used

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  • Acridinyl complex crystal, doped crystal luminescent material and preparation method and application of acridinyl complex crystal and doped crystal luminescent material
  • Acridinyl complex crystal, doped crystal luminescent material and preparation method and application of acridinyl complex crystal and doped crystal luminescent material
  • Acridinyl complex crystal, doped crystal luminescent material and preparation method and application of acridinyl complex crystal and doped crystal luminescent material

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preparation example Construction

[0040] The present invention provides a preparation method of the acridinium complex crystal described in the above technical scheme, comprising the following steps:

[0041] Acridine, cadmium chloride, and a low-carbon alcohol-water solvent (hereinafter referred to as the first solvent) are mixed (hereinafter referred to as the first mixing) for coordination crystallization to obtain the acridinyl complex crystal.

[0042] In the present invention, unless otherwise specified, the raw materials used are commercially available products well known to those skilled in the art.

[0043] In the present invention, the water in the first solvent is preferably deionized water, and the lower alcohol in the first solvent is preferably ethanol. In the specific implementation of the present invention, the volume ratio of the lower alcohol and water in the first solvent is preferably 1:1.

[0044] In the present invention, the mass ratio of the acridine to cadmium chloride is preferably 1...

Embodiment 1

[0083] Dissolve 0.183g of cadmium chloride in 10mL of water to obtain an aqueous solution of cadmium chloride; dissolve 0.179g of acridine in 10mL of ethanol to obtain an acridinium alcohol solution. Under the condition of stirring speed of 300r / min, the cadmium chloride aqueous solution was added to the acridinium alcohol solution for coordination crystallization for 3 minutes to obtain yellow needle-like microcrystals, and the solid product obtained by solid-liquid separation was washed with water and dried naturally to obtain acridine Pyridyl complex crystals.

Embodiment 2

[0085] Dissolve 0.183g of cadmium chloride and 3mg of rhodamine B in 10mL of water to obtain an aqueous solution of cadmium chloride; dissolve 0.179g of acridine in 10mL of ethanol to obtain an acridinium alcohol solution. Under the condition of a stirring speed of 300r / min, the cadmium chloride aqueous solution was added to the acridinium alcohol solution for coordination crystallization for 3 minutes to obtain red needle-like microcrystals, and the solid product obtained by solid-liquid separation was washed with water and dried naturally to obtain the mixed Miscellaneous luminescent crystal materials.

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Abstract

The invention relates to the technical field of preparation of luminescent materials, in particular to an acridinyl complex crystal, a doped crystal luminescent material and a preparation method and application of the acridinyl complex crystal and the doped crystal luminescent material. The chemical formula of the acridinyl complex crystal provided by the invention is as shown in a formula I: [CdCl2 (AD)], and in the formula I, AD is an acridine molecule. According to the acridinyl complex crystal provided by the invention, an inorganic component cadmium chloride is introduced to coordinate with acridine, and acridine molecules are fixed in a rigid framework of the complex crystal, so that the acridinyl complex crystal with long luminous life and high luminous efficiency is obtained. Results of the embodiment show that the acridinyl complex crystal provided by the invention has bright yellow fluorescence emission under excitation of a 365nm steady-state light source, the fluorescence lifetime is 20.69 ns, and the light-emitting quantum yield is 62%.

Description

technical field [0001] The invention relates to the technical field of preparation of luminescent materials, in particular to acridinium complex crystals, doped crystal luminescent materials and their preparation methods and applications. Background technique [0002] Organic light-emitting functional materials have attracted much attention due to their applications in optical waveguides, sensors, and optoelectronic devices, as well as their easily adjustable physical and chemical properties. Compared with pure inorganic materials, organic light-emitting functional materials usually have the advantages of easy structure adjustment and simple processing. However, organic light-emitting functional materials have poor thermal / optical stability due to low crystallinity, which affects their wide application in light-emitting devices. [0003] Acridine is an important class of photoelectric functional materials. The lower crystallinity directly affects the physical and chemical s...

Claims

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Application Information

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IPC IPC(8): C07F3/08C09K11/06H01L51/54
CPCC07F3/08C09K11/06C09K2211/188C09K2211/1029H10K85/381
Inventor 杨晓刚张吉蕊田旭柯窦昶勋秦建华王华瑞
Owner LUOYANG NORMAL UNIV
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