Plastic anti-crack modified fiber of cement-based material and prepn. process

A technology of cement-based materials and modified fibers, which is applied in the fields of materials science and engineering science, can solve the problems of resistance to chemical media erosion, small ultimate tensile strain, and rising costs of concrete maintenance and repair, and achieve improved frost resistance and plastic shrinkage cracking performance reduction effect

Inactive Publication Date: 2006-09-20
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, concrete also has the disadvantages of low tensile strength, small ultimate tensile strain, poor impact strength, especially high brittleness, and concrete cracking due to plastic shrinkage and drying loss before the cement hardens.
Among them, the defect of plastic shrinkage and cracking of cement concrete has a great impact on the quality of concrete engineering, especially for high-strength concrete, which may cause rework during the construction stage because it directly affects the appearance quality of the project, or bring shrinkage cracks in the plastic stage into the engineering use stage. Due to this "congenital" defect of concrete, its impermeability, frost resistance, chemical medium corrosion resistance, steel corrosion resistance and other properties are affected, resulting in a greatly shortened service life of concrete and a substantial increase in concrete maintenance and repair costs

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Modified fiber volume percentage is:

[0032] Polypropylene Fiber 95%

[0033] Modifier 5%

[0034] The polypropylene fiber adopts trilobal shape, the fiber equivalent diameter is 34μm, and the fiber length is 20mm; the modifier uses non-ionic surfactant. After mixing polypropylene fiber with 0.10% volume fraction of cement mortar (32.5 ordinary cement: medium sand: water = 1:1:0.5), the reduction rate of plastic shrinkage cracking is about 100% as measured by the plate method, which is relatively Compared with the effect of the unmodified fiber, the cracking effect of the modified fiber is about 30%.

Embodiment 2

[0036] Modified fiber volume percentage is:

[0037] Polyacrylonitrile Fiber 60%

[0038] Glass Fiber 30%

[0039] Modifier 10%

[0040] The polyacrylonitrile fiber is rectangular, the fiber equivalent diameter is 100 μm, and the fiber length is 20 mm; the glass fiber is 6% zirconia, the fiber diameter is 13 μm, and the fiber length is 10 mm; the modifier is an anionic surfactant. After the modified fiber is mixed into cement mortar (32.5 ordinary cement: medium sand: water = 1:1:0.5) at a volume fraction of 0.04%, the reduction rate of plastic shrinkage cracking is about 95% as measured by the flat plate method, which is relatively Compared with the effect of the unmodified fiber, the cracking effect of the modified fiber is about 50%.

Embodiment 3

[0042] Modified fiber volume percentage is:

[0043] Nylon Fiber 49%

[0044] Mineral Fiber 49%

[0045] Modifier 2%

[0046] The nylon fiber is round or dumbbell-shaped, with a fiber diameter of 43 μm and a fiber length of 20 mm; the mineral fiber is round, with a fiber diameter of 8 μm and a fiber length of 15 mm; the modifier is a silane coupling agent. After the modified fiber was mixed into cement concrete (32.5 ordinary cement: 5-25mm crushed stone: medium sand: water = 1: 0.75: 0.75: 0.5) at a volume fraction of 0.20%, its effect on plastic shrinkage cracking was measured by the plate method. The reduction rate is about 93%. Compared with the effect of the unmodified fiber, the cracking effect of the modified fiber is about 40%.

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Abstract

This invention is attributed to the field of materials science and engineering and concretely speaking, relates to a kind of modified fibers for preventing plastic cracking of cement-based materials (such as cement paste, mortar, concrete their composites), which comprises organic synthetic fibers, inorganic fibers or organic-inorganic hybrid fibers and modifiers. The modified fibers in this invention perform significant prevention from plastic shrinkage cracking of cement-based materials from their molding to complete solidification, and over 90% plastic cracking can be reduced by doping with the fibers compared to undoped ones. They also have an effect of reducing 30~50% more plastic cracking than unmodified fibers. This invention can be widely applied in cement-based materials engineering, such as cement-concrete roads, bridge decks, grounds, slope protection, dams, etc, so as promote project quality.

Description

technical field [0001] The invention belongs to the field of material science and engineering science and technology, and particularly relates to a modified fiber for preventing plastic shrinkage and cracking of cement-based materials (cement paste, mortar, concrete and composite materials thereof). Background technique [0002] Concrete is one of the largest and most widely used man-made building materials in the world. At present, my country's annual cement output has reached 860 million tons, and the annual concrete consumption has reached 2 billion cubic meters. For quite a long period of time in the future, concrete will still be the main building material of modern engineering construction in our country. Moreover, because it has the advantages of wide application range, cheap price, easy casting, relatively durable, and can effectively use some industrial solid waste to make energy-saving and environmentally friendly building materials, it plays an irreplaceable role...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B16/06C04B14/38
Inventor 马一平
Owner TONGJI UNIV
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