Natural gas vehicle powertrain with onboard catalytic reformer

Inactive Publication Date: 2015-06-18
EXXON RES & ENG CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The patent describes a method for reforming fuel in an internal combustion engine. The method involves using an exhaust gas recycle reformer containing a hydrocarbon-reforming catalyst composition. The exhaust gas-containing mixture includes engine exhaust gas and a first hydrocarbon-containing fuel, which has at least some methane content. The gas is converted to a hydrogen-rich gas using the catalyst composition at high temperature. The technical effect of this method is to provide a more efficient way to utilize the fuel in the engine, resulting in better performance and improved fuel economy.

Problems solved by technology

This can limit the selection of fuels, as some compositions that may be suitable from an energy content standpoint can lack appropriate combustion properties.

Method used

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  • Natural gas vehicle powertrain with onboard catalytic reformer
  • Natural gas vehicle powertrain with onboard catalytic reformer
  • Natural gas vehicle powertrain with onboard catalytic reformer

Examples

Experimental program
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Effect test

embodiment 1

[0087]A method for reforming a fuel in an internal combustion engine, said method comprising: (a) providing an exhaust gas-containing mixture to an exhaust gas recycle reformer, the exhaust gas recycle reformer comprising a reformer inlet, a reformer outlet, and a hydrocarbon-reforming catalyst composition, the exhaust gas-containing mixture comprising engine exhaust gas and a first hydrocarbon-containing fuel, the hydrocarbon-containing fuel comprising at least about 50 mol % methane, and (b) converting under reforming conditions at least a portion of the exhaust gas-containing mixture in the presence of a hydrocarbon-reforming catalyst composition comprising at least about 0.1 wt % of a hydrocarbon-reforming metal catalyst supported on a mixed metal oxide support, the mixed metal oxide support comprising at least about 20 wt % of a mixture of lanthanum oxide and aluminum oxide and at least about 10 wt % of a mixture of cerium oxide and zirconium oxide, the aluminum oxide optionall...

embodiment 2

[0088]The method of Embodiment 1, wherein the mixed metal oxide support consists essentially of the mixture of lanthanum oxide and aluminum oxide and the mixture of cerium oxide and zirconium oxide.

embodiment 3

[0089]The method of Embodiments 1 or 2, wherein the mixture of lanthanum oxide and aluminum oxide comprises about 0.4 wt % to about 15 wt % of lanthanum oxide based on the combined weight of lanthanum oxide and aluminum oxide.

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Abstract

Catalyst compositions and methods for use of such catalyst composition in the exhaust gas recycle stream of an internal combustion engine for reforming of a methane-containing fuel are provided. A reformer incorporating such a catalyst for use in an exhaust gas recycle portion of an internal combustion engine powertrain is described. A powertrain incorporating such a reformer, a method of increasing the octane rating of an exhaust gas recycle stream, and a method of operating an internal combustion engine for methane combustion are also described.

Description

CROSS REFERENCE TO RELATED APPLICATIONS[0001]This application claims the benefit of provisional U.S. Application No. 61 / 915,555, filed on Dec. 13, 2013, the entirety of which is incorporated herein by reference.FIELD OF THE INVENTION[0002]Embodiments of the invention relate to catalytic reforming of a mixture of a methane-containing fuel and internal combustion engine exhaust gas. In particular, embodiments of the invention relate to catalytic reforming of such engine exhaust gas recycle that contains an amount of methane and higher molecular weight organics sufficient to sustain the formation of H2 and CO (and / or CO2) in the reformer.BACKGROUND[0003]Conventional internal combustion engine designs can typically include a single fuel for combustion within the engine cylinders. This can require careful selection of an appropriate fuel, so that the fuel has appropriate combustion properties, such as a suitable Research Octane Number or a suitable flame speed. This can limit the selecti...

Claims

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Application Information

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IPC IPC(8): C10L3/10
CPCC10L3/10C10L2230/22C10L2270/02C10L2290/02B01J23/63B01J29/068B01J29/743B01J2523/00C01B3/40C01B2203/0233C01B2203/0238C01B2203/1047C01B2203/1064C01B2203/1082C01B2203/1241C01B2203/1247F02B37/013F02B43/12F02B51/02F02B2043/103F02M21/0227F02M26/05F02M26/20F02M26/35F02M26/36F02M27/02Y02P20/141Y02P20/52Y02T10/12Y02T10/30B01J2523/31B01J2523/3706B01J2523/3712B01J2523/48B01J2523/822B01J21/04B01J21/08B01J23/10B01J23/464B01J29/005B01J29/44B01J29/70B01J29/80B01J29/85C01B2203/107C01B2203/84C10L3/00C10L3/08C10L2290/06C10L2290/24F01N3/20F02B61/02
InventorBRODY, JOHN FRANCISMADIARA, PAUL DMITRIWEISSMAN, WALTERCHOI, EUGINEBEUTEL, TILMAN WOLFRAMLI, WENJUN
OwnerEXXON RES & ENG CO