32 results about "Electrolyte cation" patented technology

The present invention proposes a secondary battery electrolyte, a preparation method thereof and a battery, wherein the electrolyte includes a solvent, an electrolyte, and an additive, wherein the solvent includes carbonate, fluorinated ether, and chloroalkane; the additive includes nitrate and sulfur dioxide . The solvent and the additive of the present invention can play a synergistic effect and change the solvation structure of the electrolyte. On the one hand, it can improve the conductivity of the electrolyte and reduce the migration resistance of electrolyte cations, thereby reducing the polarization of the battery during fast charging and improving Fast charge capacity; on the other hand, it can inhibit solvent co-intercalation, thereby improving the fast charge cycle performance of the battery. The additive of the present invention can participate in the SEI film-forming reaction on the surface of the negative electrode during charging, making the SEI film more stable, thereby further improving the fast charging cycle performance of the battery. The technical problems of low fast-charging capacity, fast-charging cycle capacity attenuation, and short life of the battery are solved through the joint action of each component. The invention also provides a preparation method of the electrolyte and a battery containing the electrolyte.

The invention discloses a composite electrode material and its application, wherein the composite electrode material includes: a carbon-based active material; and a solid electrolyte material, the solid electrolyte material includes an ion-conducting matrix and an ionic compound for providing electrolyte anions and electrolyte cations . The composite electrode material directly mixes the carbon-based active material with the solid electrolyte material to form an ion conduction channel in the electrode, which saves the usual process of the electrolyte penetrating into the electrode to form an ion conduction channel for the electrode, and also avoids the solid The problem of small electrode thickness caused by electrolyte material is difficult to penetrate.

Methods and systems for electrolyte regeneration are provided, which regenerate a spent alkaline electrolyte (SE) comprising dissolved aluminum hydrates from an aluminum-air battery, by electrolysis, to precipitate aluminum tri-hydroxide (ATH) and form regenerated alkaline electrolyte, and adding a same-cation salt to an anolyte used in the electrolysis to supplant a corresponding electrolyte cation. The regeneration may be carried out continuously and further comprise mixing the SE and the same-cation salt in a salt tank configured to deliver the anolyte, removing the regenerated alkaline electrolyte from a catholyte tank configured to deliver the catholyte, and filtering the ATH from a solution delivered from the salt tank to the anolyte. Optionally, the salt may be a buffering salt, and in some cases chemical reactions may be used to enhance the regeneration by electrolysis.

The invention discloses a preparation method of a molybdenum disulfide nanosheet material, which is prepared by an electrochemical method, using an inert transition metal as an electrode, and an external circuit device regularly controls the directional reaction time of the cathode and anode and the electrode switching time interval, and uses an electrolyte as a medium to Molybdenum disulfide is prepared into a reaction slurry, and the molybdenum disulfide nanosheet material is obtained by controlling electrolyte cations to repeat intercalation-deintercalation reactions, centrifugation, drying and other post-processing steps. Most of the molybdenum disulfide nanosheet materials prepared by the invention are single-layer molybdenum disulfide two-dimensional materials, which belong to nanomaterials with direct band gaps, can be used as fluorescent materials, and can also be popularized and applied in light-emitting devices, photoelectric conversion, energy storage, catalysis, etc. field. The method is an environment-friendly, energy-saving, and easy-to-implement intelligent control nanomaterial preparation method.

The invention provides a solvent co-intercalated sodium ion capacitor comprising an anode, a cathode, a sodium auxiliary electrode, an electrolyte, and a diaphragm between the anode and the cathode. The concentration of the electrolyte is between 0.5 and 3mol / L. A solvent is selected from one or more of a group including diethanol dimethyl ether, tetraethanol dimethyl ether, and tetrahydrofuran. The electrolyte positive ions in the electrolyte are sodium ions. The negative ions in electrolyte are hexafluorophosphate, tetrafluoroborate, triflate, and perchlorate. The diaphragm is biomass cellulosic material and has 10 to 100 micrometers of thickness, 30% to 95% of porosity, and 20 to 200 nanometers of average diameters. The solvent used in the electrolyte and the sodium ions can be co-intercalated into graphite-kind cathode material and a problem is effectively solved that sodium ions cannot be intercalated into the graphite-kind cathode material in a conventional esters solvent. The biomass cellulosic diaphragm material improves the ionic conductivity of the electrolyte so as to further improve the large-current charging and discharging capability of the sodium ion capacitor, and is low in cost. The sodium ion capacitor is simple in production process, high in specific energy, good in cyclic stability, and has good application prospect in the field of new energy.

The invention discloses a chelating adsorbent for blood purification and a preparation method for the chelating adsorbent. The adsorbent comprises a macromolecular carrier which is grafted with a copolymer of maleic anhydride and styrene, vinyl acetate or vinyl pyrrolidone. According to an adsorbing material, a charge transfer complex can be formed by virtue of maleic anhydride and vinyl monomers and is grafted with a copolymer of maleic anhydride, so that the grafting amount of maleic anhydride is improved to a great extent; after the adsorbing material is hydrolyzed, the hydrophilicity of the adsorbing material can be improved so as to improve the blood compatibility. The maleic anhydride obtained by hydrolysis can be chelated with heavy metal ions in blood to form a relatively stable seven-membered ring structure, so that the selective absorption capacity on the heavy metal ions is improved, and therefore, other electrolyte cations are not greatly influenced while the heavy metal ions are removed from blood.

The invention provides a general method for measuring material surface property parameters. The method can measure the surface electric potential of different types of materials under different conditions accurately. The method comprises the following steps: performing saturation treatment on the material surface to be determined; mixing the saturated material which is subjected to the saturationtreatment and is to be determined with an indicating electrolyte solution; measuring equilibrium concentration values of cations and hydrogen ions in indicating electrolyte of the body solution of the mixture; calculating the material surface electric potential according to the equilibrium concentration values of the cations in the indicating electrolyte; in a further technical proposal, calculating material specific surface area and surface charge density according to the material surface potential, calculating material surface electric field intensity according to the material surface charge density, and calculating total material surface charge amount according to the surface charge density and the specific surface area. The method is obtained in the relevant technology field for the first time, which can be applied widely for measuring the surface property parameters of materials with different charge types and under different conditions, and can realize combined measurement.

The invention relates to the field of new materials, and discloses a method for preparing a powder material with an electrochemical cathode. By using an inert electrode as an anode, a massive metal, semiconductor and alloy as a cathode, and a lithium salt / sodium salt / quaternary ammonium salt organic solution, pyrrole, quaternary ammonium salt or piperidine ionic liquid or strongly alkaline water solution as an electrolyte, strong cathode polarization is carried out under constant voltage; under the action of the strong cathode voltage, the massive metal, semiconductor and alloy surface forms an unstable intermediate Mx+Ny- (M+ is an electrolyte cation, and N represents metal, semiconductor or alloy) and becomes corroded; the intermediate is very unstable in the electrolyte, and is quickly decomposed to generate an atomic cluster; the atomic cluster continues aggregate to obtain a nanoparticle sol; and finally, the sol is centrifuged / washed, and dried to obtain the powder material. The prepared powder material can be widely used in the fields of lithium ion batteries, supercapacitors, (electric) catalysis, biosensing, photovoltaic devices, micro-electronics and the like.

The present invention provides an electrolytic solution comprising carboxylate and methyl halide. Carboxylate can be combined with the cation of the electrolyte, and halogenated alkanes are small in size and can act as lubricants to reduce ion migration resistance, thereby improving the ionic conductivity of the electrolyte; potassium salt additives can change the internal electrolyte of the electrolyte The solvation status of cations and the film-forming reaction form at the electrode interface enable the formation of a thin and stable SEI film on the surface of the negative electrode, reducing the resistance of ions intercalating into the negative electrode; AgPF 6 The additive can be reduced to form nano-Ag particles on the surface of the negative electrode, which reduces the charge transfer resistance of the SEI film and reduces the ion intercalation / deintercalation resistance; through the joint action of carboxylate, methyl halide, electrolyte and additives, the battery is improved in- The discharge performance and cycle performance below 40°C can still be discharged in a deep low temperature environment of -70°C. The invention also provides a preparation method of the electrolytic solution and a battery containing the electrolytic solution.