The invention particularly relates to a method for determining a
reaction rate constant of tetravalent iron and organic pollutants by using a
chemiluminescence method, and belongs to the technical field of
water quality detection. According to the method, on the basis of a
chemiluminescence reaction between Fe (IV) and
naproxen (
NAP), a target organic
pollutant (TrOC) is introduced, the
quenching effect of the target organic
pollutant on a
chemiluminescence signal is measured, and a competitive
kinetic model between the chemiluminescence
quenching capacity (CLQC) and a secondary
reaction rate constant (kFe (IV), TrOC) of Fe (IV) on the target
pollutant is constructed. According to the method, the concentration of Fe (IV) does not need to be monitored in real time, and the reaction activity between Fe (IV) and various pollutants can be directly and rapidly measured only by comparing the
intensity change of the chemiluminescence signals when the target pollutants exist and do not exist.