Formaldehyde-free color-fixing agent of active dye

A formaldehyde-free color-fixing agent and reactive dye technology, applied in dyeing, textiles and papermaking, etc., can solve poor diffusion performance, unsatisfactory wet rubbing fastness and washing fastness, and can only form a film on the fiber surface Fixation and other problems to achieve the effect of improving color fastness

Inactive Publication Date: 2013-07-10
SUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current formaldehyde-free color fixing agent has been widely used in the dyeing of cotton fabrics with reactive dyes, but the wet rubbing fastness and color fastness to washing are not ideal. , the diffusion performance is poor, it is difficult to penetrate into the interior of the fiber and form a lake with the dye, and can only be fixed on the surface of the fiber; the other part is too small because of the molecular weight, although it can enter the interior of the fiber to form a lake with the dye, but due to the small molecular weight As a result, the intermolecular force is small, the color lake formed with the dye is unstable, it is easy to detach from the fiber, and the film-forming property on the fiber surface is poor, and it cannot be highly cross-linked and fixed on the fiber surface
In a word, no formaldehyde-free color fixing agent with too large or too small molecular weight can not improve the wet rubbing fastness and washing fastness of cotton fabrics dyed with reactive dyes.

Method used

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  • Formaldehyde-free color-fixing agent of active dye
  • Formaldehyde-free color-fixing agent of active dye
  • Formaldehyde-free color-fixing agent of active dye

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Synthesis of Compound A:

[0039] Simplify the structure of 0.5 moles as H 2 NCH 2 CH 2 NHCH 2 CH 2 NH 2 Put the diethylenetriamine compound, dicyandiamide, and ammonium chloride into the reaction flask, stir, heat up to 130°C, and keep the temperature for 3 hours to react at this temperature to obtain the deamination polycondensation product of diethylenetriamine and dicyandiamide. Then react the polycondensate with epichlorohydrin in an aqueous medium at a mass ratio of 1:0.8, the reaction temperature is 70°C, and the reaction time is 4 hours, then allow it to cool to room temperature, and add an appropriate amount of hydrochloric acid to adjust the pH to 5 , to obtain compound A, its structural formula is:

[0040]

[0041] Among them, m is the degree of polymerization.

[0042] Synthesis of Compound B:

[0043] First, the simplified structural formula of 0.5 mole is H 2 NCH 2 CH 2 NHCH 2 CH 2 NH 2 The diethylenetriamine compound and hydrochloric acid ...

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PUM

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Abstract

The invention discloses a formaldehyde-free color-fixing agent of an active dye, which is prepared with 2-4 compounds. The formaldehyde-free color-fixing agent comprises a reactive functional group, has high cationic performance, and can effectively improve the dry rubbing fastness, wet rubbing fastness, color fastness to washing of the fabric dyed with the active dye. Moreover, the formaldehyde-free color-fixing agent has little effect on the color light of the fabric.

Description

technical field [0001] The invention relates to a color-fixing agent, in particular to an formaldehyde-free color-fixing agent for reactive dyes, and belongs to the technical field of synthesis of textile printing and dyeing auxiliaries. Background technique [0002] Cotton textiles are more and more widely used in people's life due to their excellent hygroscopicity and comfort. There are several types of dyes used in dyeing cotton textiles, including reactive, direct, vulcanized, and vulcanized. Among these dyes, reactive dyes have become the most widely used dyes in cotton fabric dyeing because of their advantages such as complete color spectrum, bright color, reasonable price and convenient use. However, after dyeing cotton fabrics with reactive dyes, its color fastness is average, especially the wet rubbing fastness and color fastness to washing after dyeing medium and dark colors are poor. Adsorbed on the fiber surface but not chemically bonded to the fiber, these unb...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06P5/08D06P5/22D06P3/66
Inventor 周向东杨海涛
Owner SUZHOU UNIV
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