The invention relates to a preparation method and an apparition of a wet rubbing fastness improver containing copper microcapsules. The preparation method comprises the following steps: (1), silane modified ultrafine copper nanopowder is prepared; (2), the ultrafine copper nanopowder is ground and dried to constant weight; (3), the dried ultrafine copper nanopowder, 2,2'-azodiisobutyronitrile, divinyl benzene, butyl acrylate, methyl methacrylate and distilled water are mixed uniformly, tricalcium phosphate is added, and the mixture is subjected to ultrasonic vibration to obtain a dispersing liquid; (4) the dispersing liquid is placed into a flask with four necks to be subjected to heating, micro-suspension polymerization, heating and curing, and a product is washed with excessive hydrochloric acid solution and then washed to neutral to obtain the wet rubbing fastness improver containing the copper microcapsules. The prepared wet rubbing fastness improver containing the copper microcapsules can improve the wearability of fabric dyed with reactive dye, and the preparation method has the characteristics of simplicity, low cost, little time and labor investment, low toxicity of synthetic raw materials and reduction of environmental pollution.