2-Acetylpyridine benzohydrazide molybdenum complex and preparation method thereof
A kind of technology of acetyl pyridine hydrazide, molybdenum complex, applied in 2-acetyl pyridine benzoyl hydrazide molybdenum complex and preparation field thereof, can solve the problem of unseen molybdenum Schiff base complex and the like problem, to achieve the effect of excellent catalytic performance, low cost and simple operation
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0018] Weigh 10 mmoles of benzoylhydrazine, put it into a round-bottomed flask (50 ml) containing 20 milliliters of absolute ethanol, heat and stir at 50° C., add 10 mmoles of 2-acetylpyridine after the benzoylhydrazine is completely dissolved, After stirring for 1 hour, it was allowed to stand still, and white needle-like crystals precipitated after 7 days. Filtrate with suction and wash with a small amount of ethanol to obtain 2-acetylpyridine benzohydrazine Schiff base complex.
[0019] Weigh 5mmol of 2-acetylpyridinebenzohydrazide Schiff base complex, put it into a round-bottomed flask (50ml) containing 15ml of absolute ethanol, heat and stir at 75°C, and wait until 2-acetylpyridinebenzohydrazide Add 5mmol of molybdenum acetylacetonate after complete dissolution, orange powder is precipitated, continue to heat and stir for 2 hours, filter with suction, wash with ethanol, and dry in vacuum at 40°C to obtain an orange powder product. Its structural formula is as follows, and...
Embodiment 2
[0022] Weigh 10 mmoles of benzoylhydrazine, put it into a round-bottomed flask (50 ml) containing 20 milliliters of pyridine, heat and stir at 50° C., add 10 mmoles of 2-acetylpyridine after the benzoylhydrazide is completely dissolved, and stir for 1 After standing for one hour, white needle-like crystals precipitated after 7 days. Filtrate with suction and wash with a small amount of ethanol to obtain 2-acetylpyridine benzohydrazine Schiff base complex.
[0023] Weigh 5mmol of 2-acetylpyridinebenzohydrazide Schiff base complex, put it into a round-bottomed flask (50ml) containing 15ml of pyridine, heat and stir at 75°C until 2-acetylpyridinebenzohydrazide is completely dissolved Then add 5mmol of molybdenum acetylacetonate, orange powder is precipitated, continue to heat and stir for 2 hours, then suction filter, wash with pyridine and dry in vacuum at 40°C to obtain the product, its structural formula is as follows, its infrared analysis spectrum and figure 1 resemblance. ...
Embodiment 3
[0026] Take tert-butyl hydroperoxide, n-propanol and the 2-acetylpyridine benzohydrazide molybdenum complex synthesized in [Example 1] and put them into a high-pressure reactor, and start heating and stirring after sealing the reactor. When the preset 100°C is reached, the high-pressure pump pumps in propylene, and the amount of propylene is determined by the pumped volume. Reaction timing, after reaching 2 hours, take off the reactor, cool to 10-15°C with ice water, and take the liquid phase into a frozen sampler. Continue to freeze the sampler at minus 20°C for 30 minutes, then unscrew the air valve, slowly release the propylene in the sampler, open the sampler, quickly transfer the remaining liquid to the chromatographic sampling bottle, seal it, and perform chromatographic analysis.
[0027] Reaction conditions: reaction temperature 100°C, reaction time 2 hours, rotating speed 540rpm, tert-butyl hydroperoxide (TBHP) addition 70 millimoles, n-propanol addition 50 millimoles...
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com