High-voltage anode material for lithium ion battery and lithium ion battery comprising same

A lithium-ion battery, cathode material technology, applied in battery electrodes, secondary batteries, circuits, etc., can solve problems such as inability to effectively improve battery volumetric energy density, poor thermal stability, and easy structural changes, and achieve good thermal stability. and cycle performance, the uniformity is easy to control, and the effect of improving the cycle performance

Active Publication Date: 2013-04-24
DONGGUAN AMPEREX TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] One of the purposes of the present invention is to: address the deficiencies in the prior art, and provide a high-voltage lithium-ion battery positive electrode material and a lithium-ion battery comprising the material, the positive electrode material can charge at a higher cut-off voltage (4.4V- 4.7V), and has high thermal stability, so that the lithium-ion battery using this positive electrode material has a higher volumetric energy density and better cycle performance, thereby overcoming the thermal stability of the positive electrode material in the prior art The performance is poor, and the structure is easy to change when used under high voltage. Even if it is coated, it cannot effectively improve the volume energy density of the battery.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Embodiment 1: The positive electrode material of a high-voltage lithium-ion battery provided in this embodiment includes material A and material B, and the mass ratio of material A to material B is 8:2.

[0034] Among them, material A has a core-shell structure, and its core layer material is Li 1.02 co 0.98 Al 0.005 Mg 0.01 Ti 0.005 o 2 Particles, median diameter D 50 is 20μm; the structural formula of its shell material is LiNi 0.6 mn 0.4 PO 4 ; The structural formula is LiNi 0.6 mn 0.4 PO 4 The shell material accounts for 2 wt% of the material A, and the thickness of the shell material is 100 nm.

[0035] Material B has a core-shell structure, and its core layer material is Li 1.02 co 0.98 Al 0.005 Mg 0.01 Ti 0.005 o 2 Particles, median diameter D 50 is 5 μm; the structural formula of its shell material is Li 0.7 Al 0.9 Zr 0.15 o 2 , the structural formula is Li 0.7 Al 0.9 Zr 0.15 o 2 The shell material accounts for 2 wt% of the material B, ...

Embodiment 2

[0036] Embodiment 2: The positive electrode material of a high-voltage lithium-ion battery provided in this embodiment includes material A and material B, and the mass ratio of material A to material B is 2:8.

[0037] Among them, material A has a core-shell structure, and its core layer material is Li 1.07 co 0.985 Al 0.005 La 0.005 Sr 0.005 o 2 Particles, median diameter D 50 is 16 μm; the structural formula of its shell material is LiNi 0.7 mn 0.3 PO 4 ; The structural formula is LiNi 0.7 mn 0.3 PO 4 The shell material accounts for 0.1 wt% of the material A, and the thickness of the shell material is 5 nm.

[0038] Material B has a core-shell structure, and its core layer material is Li 1.07 co 0.985 Al 0.005 La 0.005 Sr 0.005 o 2 Particles, median diameter D 50 is 3 μm; the structural formula of its shell material is Li 0.1 Al 0.9 Zr 0.3 o 2 , the structural formula is Li 0.1 Al 0.9 Zr 0.3 o 2 The shell material accounts for 8 wt% of the material ...

Embodiment 3

[0039] Embodiment 3: The positive electrode material of a high-voltage lithium-ion battery provided in this embodiment includes material A and material B, and the mass ratio of material A to material B is 5:5.

[0040] Among them, material A has a core-shell structure, and its core layer material is Li 0.98co 0.9 Al 0.03 Zr 0.01 Mg 0.06 o 2 Particles, median diameter D 50 is 25 μm; the structural formula of its shell material is LiNi 0.9 mn 0.1 PO 4 ; The structural formula is LiNi 0.9 mn 0.1 PO 4 The shell material accounts for 8 wt% of the material A, and the thickness of the shell material is 800nm.

[0041] Material B has a core-shell structure, and its core layer material is Li 0.98 co 0.9 Al 0.03 Zr 0.01 Mg 0.06 o 2 Particles, median diameter D 50 is 6 μm; the structural formula of its shell material is Li 0.8 Al 0.8 Zr 0.2 o 2 , the structural formula is Li 0.8 Al 0.8 Zr 0.2 o 2 The mass percentage of the shell material in material B is 0.1 wt%...

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Abstract

The invention belongs to the technical field of lithium ion batteries, and particularly relates to a high-voltage anode material for a lithium ion battery. The anode material comprises a material A and a material B, wherein the material A has a core-shell structure, a core layer material is lithium cobalt oxide particles formed by primary particles, the median particle diameters D50 of the lithium cobalt oxide particles are 15-25 microns, and the structure formula of a core-shell material is LixNiyMnzPO4; the material B has a core-shell structure, the core layer material is the lithium cobalt oxide particles formed by secondary particles, and the median particle diameters D50 of the lithium cobalt oxide particles are is 3-9 microns; and the structure formula of the core-shell material is LiwAlpZrqO2, and the mass ratio of the material A to the material B is (0.1-10) to 1. Compared with the prior art, the high-voltage anode material for the lithium ion battery provided by the invention has the advantages that the large and small lithium cobalt oxide particles are combined reasonably, different core layer materials can be arranged on the surfaces of the lithium cobalt oxide particles, and the secondary particles are selected as the small lithium cobalt oxide particles, so that the cycle performance and the safety performance of the anode material under high voltage are notably improved.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to a high-voltage lithium ion battery cathode material and a lithium ion battery containing the material. Background technique [0002] Lithium-ion batteries generally include: a positive electrode sheet, a negative electrode sheet, a separator spaced between the positive and negative electrode sheets, and an electrolyte, wherein the positive electrode sheet includes a positive electrode current collector and a positive electrode material layer distributed on the positive electrode current collector, and the negative electrode sheet It includes a negative electrode current collector and a negative electrode material layer distributed on the negative electrode current collector. At present, the commonly used lithium-ion cathode material is LiCoO 2 、LiNi 1 / 3 co 1 / 3 mn 1 / 3 o 2 , LiMn 2 o 4 and LiFePO 4 Wait. [0003] The above several cathode material...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/58H01M10/0525
CPCY02E60/122Y02E60/10
Inventor 庞佩佩
Owner DONGGUAN AMPEREX TECH
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