Polyolefin/styrene based resin composition and preparation method thereof

A technology of styrene-based resin and styrene copolymer, which is applied in the field of polyolefin/styrene-based resin composition and its preparation, can solve problems such as poor compatibility, complex synthesis process, and poor material performance, and achieve excellent mechanical properties , excellent strength, good toughness and chemical resistance

Active Publication Date: 2013-07-03
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polyolefin plastic is a general-purpose plastic, because of its relatively simple synthesis process, low price, excellent performance, and wide application range; styrene-based resin is an engineering plastic with excellent performance, and the typical product is acrylonitrile-butadiene-styrene three Meta-copolymer, this product has excellent chemical resistance, formability, high and low temperature toughness, but its synthesis process is complicated, and its price is more expensive than polyolefin, which limits its use
In order to better integrate the advantages and properties of the two materials, many scholars have studied the alloy materials of the two products. However, it is well known that polyolefins and styrene-based resins have poor compatibility. If the two are simply melted and mixed, the obtained The product will delaminate to form two phases, and the material performance is extremely poor
In the Chinese patent that application number is 200510023968.7, PP (polypropylene) and ABS (acrylonitrile-styrene-butadiene copolymer) nano-filler alloy and its preparation method obtain a kind of PP and ABS nano-filler alloy, but the Affected by the formula and processing technology design in the invention, the ratio of the two main ingredients is in a relatively narrow range. In the actual application process, the scope of use has great limitations

Method used

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  • Polyolefin/styrene based resin composition and preparation method thereof
  • Polyolefin/styrene based resin composition and preparation method thereof
  • Polyolefin/styrene based resin composition and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] (1) Weigh 100 parts of polypropylene copolymer, 800 parts of acrylonitrile-butadiene-styrene copolymer, 50 parts of compatibilizer PP-G, 40 parts of toughening agent butadiene copolymer 181H, processing aid 5 parts of EBS, 2 parts of main antioxidant auxiliary agent 1010 and 3 parts of auxiliary antioxidant 168.

[0027] (2) put the polypropylene copolymer, acrylonitrile-butadiene-styrene copolymer, compatibilizer, toughening agent, anti-oxidation aid, processing aid weighed in the first step together into a rotating speed of 150 Mix thoroughly in a high-speed mixer at rpm for 3 minutes.

[0028] (3) Use a precise metering and conveying device to send the mixed material in the second step into the twin-screw extruder, and through the shearing action of the screw, fully mix, wherein the aspect ratio of the twin-screw extruder is 40 , the screw speed is 300 rpm, the working temperature range of the twin-screw extruder is 180°C at the feeding port, 195°C at the metering s...

Embodiment 2

[0031] (1) Weigh 200 parts of polypropylene copolymer, 650 parts of acrylonitrile-butadiene-styrene copolymer, 50 parts of compatibilizer PP-G, 90 parts of toughening agent, 5 parts of processing aid EBS, main antibiotic 2 parts of oxidation aid and 3 parts of auxiliary antioxidant.

[0032] (2) The polypropylene copolymer, acrylonitrile-butadiene-styrene copolymer, compatibilizer, toughening agent, anti-oxidation aid and processing aid taken in the first step are put into together and the rotating speed is 120 Mix thoroughly in a high-speed mixer at rpm for 3 minutes.

[0033] (3) Use a precise metering and conveying device to send the mixed material in the second step into the twin-screw extruder, and through the shearing action of the screw, fully mix, wherein the aspect ratio of the twin-screw extruder is 40 , the screw speed is 300 rpm, the working temperature range of the twin-screw extruder is 175°C at the feeding port, 190°C at the metering section, 195°C at the melti...

Embodiment 3

[0036] (1) Weigh 400 parts of polypropylene copolymer, 400 parts of acrylonitrile-butadiene-styrene copolymer, 50 parts of compatibilizer PP-G, 50 parts of compatibilizer ABS-G, toughening agent butadiene 90 parts of quasi-copolymer 181H, 5 parts of processing aid EBS, 2 parts of main antioxidant auxiliary agent and 3 parts of auxiliary antioxidant.

[0037] (2) put the polypropylene copolymer, acrylonitrile-butadiene-styrene copolymer, compatibilizer, toughening agent, anti-oxidation aid, processing aid taken in the first step together into a rotating speed of 100 Mix thoroughly in a high-speed mixer at rpm for 3 minutes.

[0038] (3) Use a precise metering and conveying device to send the mixed material in the second step into the twin-screw extruder, and through the shearing action of the screw, fully mix, wherein the aspect ratio of the twin-screw extruder is 40 , the screw speed is 300 rpm, the working temperature range of the twin-screw extruder is 180°C at the feeding ...

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Abstract

Belonging to the technical field of high polymer materials, the invention relates to a polyolefin/styrene based resin composition and a preparation method thereof. The composition is prepared from the following components by weight part: 100-800 parts of polyolefin; 100-800 parts of styrene based resin; 30-100 parts of a compatilizer; 30-200 parts of a toughening agent; 5-30 parts of a reinforcing agent; 3-10 parts of an antioxidant aid; and 2-5 parts of a processing aid. The polyolefin/styrene based resin composition prepared by the invention has stable mechanical properties. Compared with styrene based resin, the composition maintains comparable properties, and has an obvious price advantage, can partially or completely replace styrene based resin, and the economic benefits are significant. The polyolefin/styrene based resin composition provided in the invention is prepared by a twin-screw extrusion technology. Lateral forced feeding is preferably adopted in the production process, and the reinforcing agent can be dispersed better, so that the product can have excellent comprehensive properties.

Description

technical field [0001] The invention relates to the technical field of polymer materials, and relates to a polyolefin / styrene-based resin composition and a preparation method thereof. Background technique [0002] Polyolefin plastic is a general-purpose plastic, because of its relatively simple synthesis process, low price, excellent performance, and wide application range; styrene-based resin is an engineering plastic with excellent performance, and the typical product is acrylonitrile-butadiene-styrene three This product has excellent chemical resistance, formability, and high and low temperature toughness, but its synthesis process is complicated and its price is more expensive than polyolefins, which limits its use. In order to better integrate the advantages and properties of the two materials, many scholars have studied the alloy materials of the two products. However, it is well known that polyolefins and styrene-based resins have poor compatibility. If the two are si...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/14C08L55/02C08L25/12C08L51/00B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/875B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895B29C2948/92904
Inventor 李术邵灵芝杨莺
Owner HEFEI GENIUS NEW MATERIALS
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