Waste utilization based environment friendly phosphate fertilizer, preparation method and application thereof

An environmentally friendly, phosphate fertilizer technology, applied in the directions of phosphate fertilizer, application, Thomas phosphate fertilizer, etc., can solve the problems of increasing the available phosphorus content of plants, insufficient activation effect, heavy metal pollution, etc. effect of demand

Inactive Publication Date: 2016-01-13
HUNAN SOIL & FERTILIZER INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Now this method of using microorganisms to activate phosphorus in phosphate minerals is also very common. However, these methods will convert heavy metals in phosphate minerals into unstable forms, and there is a potential risk of heavy metal pollution.
It has also been reported that some minerals mixed with phosphate ore can increase the activity of phosphorus in phosphate ore. For example, the results of field experiments show that the application of silicon fertilizer has the possibility of increasing the phosphorus content available to plants. A.Hall et al. also proposed that after the application of silicon fertilizer There is a possibility of ion exchange between silicate ions and phosphate ions, but these reports are only general, especially in the selection of activating minerals and the activation mechanism, which needs further research, and the activation effect is not obvious enough.

Method used

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  • Waste utilization based environment friendly phosphate fertilizer, preparation method and application thereof
  • Waste utilization based environment friendly phosphate fertilizer, preparation method and application thereof
  • Waste utilization based environment friendly phosphate fertilizer, preparation method and application thereof

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Embodiment 1

[0027] An environment-friendly phosphate fertilizer based on waste utilization of the present invention is mainly prepared by mixing liquid active silicon-rich substances and phosphorus-containing waste minerals, and activating phosphorus-containing waste minerals with liquid active silicon-rich substances.

[0028] Phosphorus-containing waste minerals in the present embodiment adopt phosphorus-containing slag from the phosphate industry (Calcium Silicate Company, the U.S., Tennessee), and respectively adopt monosilicic acid solution (Zumsil, TerraTech.Inc., U.S., Florida) , diatomite (Palkarramine, Australia, northern Queensland) as rich in active silicon material, wherein diatomite is as a contrast, specifically prepared according to the following steps:

[0029] a) preparing phosphorus-containing slag, grinding the phosphorus-containing slag to increase its specific surface area; controlling the particle size of the phosphorus-containing slag to 0.001-5mm;

[0030] b) fully...

Embodiment 2

[0047] This embodiment adopts phosphate waste (TPR) from the Republic of Tunisia, and the water-extracted state and the acid-extracted state of heavy metals Cd, Co, Cr, Pb, Hg and Ni in this phosphate waste have been determined (the The heavy metal content is shown in the following table 4), the water extraction state is extracted with deionized water, and the acid extraction state is extracted with 0.1MHCl and 2MHNO 3 Extraction, the water-extracted state is the soluble part, and the corresponding acid-extracted state is the potentially mobile part. 2g of phosphate waste was added to 20ml of solution and mixed for 1h, then centrifuged at 6000g for 15min to get the supernatant, and the heavy metal content was determined by ICP-OES (PerkinElmer Optima5300DV).

[0048] Table 4. Mobile heavy metal content in phosphate waste (TPR) from the Republic of Tunisia

[0049]

[0050] Using a high-concentration monosilicic acid solution as a material rich in active silicon, a high-con...

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Abstract

The invention discloses a waste utilization based environment friendly phosphate fertilizer, a preparation method and application thereof. The environment friendly phosphate fertilizer is prepared mainly by subjecting a liquid state active silicon rich substance and a phosphorus containing waste mineral to mixed culture, and activating the phosphorus containing waste mineral with the liquid state active silicon rich substance. The specific preparation method consists of: firstly grinding the phosphorus containing waste mineral to increase the specific surface area; fully mixing the phosphorus containing waste mineral with the liquid state active silicon rich substance; adding water into the mixture to start culture incubation; performing drying at the end of culture incubation; and subjecting the dried mixture to granulation, thus obtaining the environment friendly phosphate fertilizer. The environment friendly phosphate fertilizer prepared by the method provided by the invention can be applied as a crop composite phosphor-silicon fertilizer. The technical scheme involved in the invention can stimulate the activity of phosphorus, also can reduce the toxicity of heavy metals, ensures food safety and promotes the growth of crops.

Description

technical field [0001] The invention belongs to the technical field of fertilizer application, and in particular relates to an environment-friendly phosphate fertilizer and its preparation method and application. Background technique [0002] Phosphorus is an essential nutrient for plants and animals. Most of the world's phosphorus is consumed by food crops in the primary form of NPK fertilizers. Phosphate ore is the only important source of phosphorus in the world. With the continuous exploitation of phosphate ore resources, phosphate ore resources are becoming less and less. According to conservative estimates, global phosphate ore resources are only enough for 30-40 years of development, and optimistic estimates are not more than 100. Therefore, developing and utilizing phosphorus-containing slag resources, improving the phosphorus grade of phosphate mines, and improving the availability of phosphorus in plants are one of the methods to solve this major problem. [0003...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05B5/00
Inventor 纪雄辉柳赛花弗拉基米尔·马基琴科夫
Owner HUNAN SOIL & FERTILIZER INST
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