A kind of mesoporous catalyst with hydrothermal stability, its preparation method and the method for preparing bio-oil by using it to catalyze hydrothermal liquefaction microalgae
A technology of hydrothermal stability and hydrothermal liquefaction, applied in organic compound/hydride/coordination complex catalysts, chemical instruments and methods, physical/chemical process catalysts, etc., can solve poor hydrothermal stability, skeleton collapse, etc. problems, to improve the quality of bio-oil, reduce energy consumption, and alleviate the shortage of fossil energy
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[0032] The mesoporous catalyst with high hydrothermal stability of the present invention, its preparation method and the method of using it to catalyze hydrothermal liquefaction of microalgae to prepare bio-oil are described in detail below in conjunction with examples and accompanying drawings.
[0033] Catalyst preparation example
[0034] Dry a certain amount of SBA-15 in vacuum at 110°C for 12 hours, add a certain amount of dichloromethane and a certain amount of hydrosilane after cooling to room temperature, add a certain amount of catalyst tris(pentafluorophenyl)borane after about 2 minutes, and ultrasonically treat for about 5min, and finally filtered. During the process, a large amount of dichloromethane was first used, and then washed with a large amount of n-hexane. The white solid obtained after filtration was vacuum-dried at 110°C and became a mesoporous catalyst. The name is shown in Table 1.
[0035] Table 1
[0036]
[0037] 1. Take 0.3g of SBA-15 and dry it...
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