The invention relates to the technical field of energy storage batteries, and discloses an aluminum ion battery and a positive electrode material CoxSy@MXene thereof. The positive electrode material is prepared by in-situ growth of micro-nano cobalt sulfide on an MXene matrix material, the micro-nano cobalt sulfide is CoxSy, x is greater than 0, y is greater than 0, and the mass of the micro-nanocobalt sulfide accounts for 5%-95% of the total mass of the positive electrode material. The positive electrode material is characterized in that: the nano micro-nano cobalt sulfide directly grows onthe MXene matrix material in situ, so that the dispersity of the nano micro-nano cobalt sulfide is improved, crystal grains are refined, the conductivity can be effectively improved, and the actual capacity of the micro-nano cobalt sulfide is fully exerted; and the synergistic effect of the MXene matrix and the micro-nano cobalt sulfide is exerted, and the specific capacity and the cycling stability of the aluminum ion battery are improved. The aluminum ion battery taking the material as the positive electrode has the advantages of low price, stable circulation, wide voltage window, cleanness,environmental protection, high safety and the like, and can be applied to the fields of electronic industry, communication industry, energy reserve and the like.