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Octadecyl organic silicon wax and preparation method and application thereof

An organosilicon wax and octadecyl technology, applied in the field of octadecyl organosilicon wax and its preparation, can solve the problems of the gap between the research and application level of organosilicon wax, backward process conditions, backward production technology, etc. The effect of moisturizing and skin-friendly, good stability and stable product status

Active Publication Date: 2017-09-29
GUANGZHOU UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The production technology of organic silicon in my country is relatively backward, and the problems of high cost and low output have been difficult to overcome
However, due to the relatively late start of my country's chemical companies, there is still a significant gap between the research and application level of silicone wax and foreign countries. For example, the production scale of domestic silicone wax products is small, the yield is low, and the process conditions are relatively backward.

Method used

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  • Octadecyl organic silicon wax and preparation method and application thereof
  • Octadecyl organic silicon wax and preparation method and application thereof
  • Octadecyl organic silicon wax and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0073]Mix D4H and hydrogen-terminated silicone oil (molecular weight: 2000, purchased from Tianjin Zhiyuan Chemical Reagent Co., Ltd.) at a molar ratio of 5:1, react at 85°C for 5h under the action of catalyst sulfonated cationic resin, and distill under reduced pressure at 135°C , and filtered to obtain a hydrogen-terminated silicone oil containing active hydrogen in the side chain.

Embodiment 2

[0075] The hydrogen-terminated silicone oil containing active hydrogen in the side chain prepared in Example 1 was mixed with 1-octadecene at a molar ratio of 1:3, under the action of catalyst chloroplatinic acid, hydrosilylation reaction, and then vacuum distillation, Obtained octadecyl silicone wax.

[0076] When the hydrosilylation reaction time is 5h, the concentration of the catalyst chloroplatinic acid in the reaction system is 13mg / kg, and the vacuum distillation temperature is 150°C, the relationship between the hydrosilylation reaction temperature and the conversion rate is as follows figure 1 As shown in a, from figure 1 a It can be seen that the reaction conversion reaches the highest at 110 °C.

[0077] When the hydrosilylation reaction temperature is 130°C, the concentration of the catalyst chloroplatinic acid in the reaction system is 13mg / kg, and the vacuum distillation temperature is 150°C, the relationship between the hydrosilylation reaction time and the con...

Embodiment 3

[0081] The hydrogen-terminated silicone oil containing active hydrogen in the side chain prepared in Example 1 is mixed with 1-octadecene according to a molar ratio of 1:3, and the catalyst chloroplatinic acid (the concentration of chloroplatinic acid in the reaction system is 12mg / kg ) under the action of hydrosilylation reaction at 110°C for 9h, and then vacuum distillation at 140°C to obtain octadecyl silicone wax.

[0082] figure 2 Infrared spectra of hydrogen-terminated silicone oil and octadecyl silicone wax containing active hydrogen in the side chain. Depend on figure 2 It can be seen that the hydrogen-terminated silicone oil containing active hydrogen in the side chain is at 2178 and 889cm -1 There are two strong absorption peaks at , which are the stretching vibration peak and deformation vibration peak of the silicon-hydrogen bond. After the reaction, the disappearance of these two absorption peaks in the octadecyl silicone wax indicates that the silicon-hydroge...

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PUM

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Abstract

The invention belongs to the field of organic chemical synthesis, and particularly relates to octadecyl organic silicon wax and a preparation method and application thereof. The preparation method of the octadecyl organic silicon wax comprises the following steps: firstly, mixing D4H with hydrogen-terminated silicone oil, reacting under the action of sulfonated cationic resin serving as a catalyst, distilling under a reduced pressure, and filtering to obtain hydrogen-terminated silicone oil of which a side chain contains reactive hydrogen; then, mixing the hydrogen-terminated silicone oil of which the side chain contains the reactive hydrogen with 1-octadecene, performing a silicon-hydrogen addition reaction under the action of chloroplatinic acid serving as a catalyst at the temperature of 90 to 130 DEG C for 6 to 10 hours, and distilling under a reduced pressure after finishing the reaction to obtain the octadecyl organic silicon wax. The invention further provides an organic silicon wax emulsion containing the octadecyl organic silicon wax. The emulsion has the advantages of proper viscosity, high moisture-keeping performance, and high stability.

Description

technical field [0001] The invention belongs to the field of organic chemical synthesis, and in particular relates to an octadecyl silicone wax and its preparation method and application. Background technique [0002] Silicon (Si) is one of the basic elements on the earth and widely exists in nature in the form of compounds. Among them, silicone is mainly used in sealing, surface activity, waterproof, anti-foaming, moisture-proof, inert filling and so on. After years of research and development, the number and varieties of silicones have been increasing, and the application fields have been continuously expanded, forming an important product system in the field of new chemical materials. The excellent performance of many varieties cannot be replaced by other chemicals. [0003] The improvement of people's living standards and the advancement of science and technology have increased the demand for organic silicon materials, and the production and sales of organic silicon at ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G77/38C08G77/12C08G77/08C08G77/06C08J3/03C08L83/04A61K8/06A61K8/891A61Q19/00
CPCA61K8/06A61K8/891A61Q19/00C08G77/06C08G77/08C08G77/12C08G77/38C08J3/03C08J2383/04
Inventor 郑成宋旻子陌梅萧毛桃嫣林璟
Owner GUANGZHOU UNIVERSITY
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