Preparation method and application of blue titanium dioxide
A titanium dioxide, blue technology, applied in the field of preparation of blue titanium dioxide, can solve the problems of limited preparation and application, low photocatalytic efficiency, low utilization rate of visible light, etc., to improve photocatalytic activity and stability, enhance visible light absorption, Favorable effect on electron transport
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[0019] A preparation method of blue titanium dioxide, adding white titanium dioxide and 10%~37% formaldehyde solution into a quartz photocatalytic reactor, ultrasonically dispersing, the ratio of white titanium dioxide to formaldehyde solution is 0.08~80g / L (that is, titanium dioxide in formaldehyde solution The concentration of 0.08~80g / L), 250~400W high-pressure mercury lamp or xenon lamp ultraviolet light for 8~30min, the blue titanium dioxide can be prepared.
[0020] The white titanium dioxide is anatase phase and / or rutile phase.
[0021] A kind of application of described blue titanium dioxide in the preparation in-situ growth precious metal nanoparticle, add 2~25mmol / L PdCl to blue titanium dioxide 2 Solution, Ultrasonic Dispersion, Blue Titanium Dioxide with PdCl 2 The molar ratio is 1~10:1, adjust the pH value to 10~11 with NaOH solution, stir magnetically for 30~60min, centrifuge, disperse the solid in 35~70mL ethanol, heat at 120~180℃ for 3~5h; centrifuge The sol...
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