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Preparation method and application of blue titanium dioxide

A titanium dioxide, blue technology, applied in the field of preparation of blue titanium dioxide, can solve the problems of limited preparation and application, low photocatalytic efficiency, low utilization rate of visible light, etc., to improve photocatalytic activity and stability, enhance visible light absorption, Favorable effect on electron transport

Pending Publication Date: 2019-01-04
NANTONG UNIVERSITY
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Problems solved by technology

However, the realization of large-scale industrial applications still needs to solve the bottleneck problems of the lack of visible light-responsive catalytic materials and the low photocatalytic efficiency caused by the high recombination rate of photogenerated electrons and holes.
[0003] Titanium dioxide is the best commercial application so far, and it is also a promising photocatalytic material in the future. It has strong photocatalytic redox ability, high stability, resistance to light and chemical corrosion, low cost, reusable, and harmless to the human body. It is non-toxic and environmentally friendly, but it also has the problems of high recombination rate of photogenerated electrons and holes and low utilization rate of visible light
[0004] However, to obtain such colored titanium dioxide often requires conditions such as high temperature, high pressure and air isolation, which greatly limits its wide preparation and application.

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  • Preparation method and application of blue titanium dioxide
  • Preparation method and application of blue titanium dioxide
  • Preparation method and application of blue titanium dioxide

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Embodiment Construction

[0019] A preparation method of blue titanium dioxide, adding white titanium dioxide and 10%~37% formaldehyde solution into a quartz photocatalytic reactor, ultrasonically dispersing, the ratio of white titanium dioxide to formaldehyde solution is 0.08~80g / L (that is, titanium dioxide in formaldehyde solution The concentration of 0.08~80g / L), 250~400W high-pressure mercury lamp or xenon lamp ultraviolet light for 8~30min, the blue titanium dioxide can be prepared.

[0020] The white titanium dioxide is anatase phase and / or rutile phase.

[0021] A kind of application of described blue titanium dioxide in the preparation in-situ growth precious metal nanoparticle, add 2~25mmol / L PdCl to blue titanium dioxide 2 Solution, Ultrasonic Dispersion, Blue Titanium Dioxide with PdCl 2 The molar ratio is 1~10:1, adjust the pH value to 10~11 with NaOH solution, stir magnetically for 30~60min, centrifuge, disperse the solid in 35~70mL ethanol, heat at 120~180℃ for 3~5h; centrifuge The sol...

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Abstract

The invention discloses a preparation method and application of blue titanium dioxide. The blue titanium dioxide is prepared by: adding white titanium dioxide and 10-37% formaldehyde solution into a quartz photocatalytic reactor, dispersing by ultrasound, and exposing to ultraviolet irradiation of a high-voltage mercury lamp or xenon lamp 250-400 W for 8-30 min, wherein the concentration of the white titanium dioxide in the formaldehyde solution is 0.08-80 g / L. The blue titanium dioxide is prepared in a normal pressure and normal temperature atmosphere; the preparation method has the advantages of low cost, good simplicity and feasibility, suitability for large-scale preparation and application and the like; the prepared blue titanium dioxide is applicable to in-situ synthesis of titaniumdioxide-based nano heterojunction materials and is widely applicable to the energy and environment fields, such as photocatalytic manufacture of solar fuels and photocatalytic degradation of pollutants.

Description

technical field [0001] The invention relates to a preparation method and application of blue titanium dioxide. Background technique [0002] Energy crisis and environmental pollution are two major challenges facing human society, and photocatalytic technology provides an ideal way to solve energy and environmental problems. Photocatalytic solar fuels and photocatalytic degradation of pollutants have shown important applications in the fields of energy and the environment prospect. However, the realization of large-scale industrial application still needs to solve the bottleneck problems such as the lack of visible light-responsive catalytic materials and the low photocatalytic efficiency caused by the high recombination rate of photogenerated electrons and holes. [0003] Titanium dioxide is the best commercial application so far, and it is also a photocatalytic material with great development prospects in the future. It has strong photocatalytic redox ability, high stabili...

Claims

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Application Information

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IPC IPC(8): B01J21/06B01J23/44B01J35/02
CPCB01J21/063B01J23/44B01J35/393B01J35/00B01J35/30B01J35/39
Inventor 赵勤景丹妮戴俊峰贾雪平李梦婷顾语
Owner NANTONG UNIVERSITY
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