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Mixed gas foam cracking liquid system and preparation thereof

A foam fracturing fluid and mixed gas technology, applied in the directions of drilling compositions, chemical instruments and methods, can solve the problems of increasing the difficulty of fracturing construction, large formation damage, frictional resistance and residue damage, etc. Layer productivity, improve fracturing effect, and reduce secondary damage

Inactive Publication Date: 2019-01-18
CHINA UNIV OF PETROLEUM (BEIJING) +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Carbon dioxide foam fracturing fluid is suitable for a wide range of temperatures and can also meet high temperature requirements. However, chemical additives such as foaming agents and bactericides must be added to the fracturing fluid system. After the gel is broken, the residue content is high, it is not easy to flow back, and it will cause great damage to the formation. , and the foam gel formed by cross-linking has high viscosity and increased friction, which further increases the difficulty of fracturing construction.
In 2005, Schlumberger newly launched VES CO 2 Clean fracturing fluid technology, VES fracturing fluid effectively solves the problems of friction and residue damage, but the temperature resistance performance needs to be improved, and its high cost hinders its popularization and application
[0005] It is worth noting that at present, there is not a large amount of foam fracturing fluid using a mixture of carbon dioxide and nitrogen in China. The mixed use of the two gases can give full play to their respective advantages, more effectively improve the effect of foam fracturing, and increase reservoir productivity.

Method used

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  • Mixed gas foam cracking liquid system and preparation thereof
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Embodiment 1

[0037] A mixed gas foam fracturing fluid system, the fracturing fluid system includes a gas phase and a liquid phase, the gas phase is nitrogen, and the liquid phase is mainly composed of 1% foaming agent (cationic Gemini quaternary ammonium salt dioleyl dimethyl ammonium chloride), 0.5% thickener (NH 4 Cl), 1% foam stabilizer (silica nanoparticles with a particle size of 30-80), 50% liquid carbon dioxide and simulated formation water (91.5% active water + 2.0% KCl + 5.5% NaCl + 0.45% MgCl 2 +0.55%CaCl 2 ) composition, the gas-liquid volume ratio is 3:1.

[0038] (1) According to 91.5% active water + 2.0% KCl + 5.5% NaCl + 0.45% MgCl 2 +0.55%CaCl 2 The mass percentage of is prepared as simulated formation water;

[0039] (2) Add 0.5% thickener (NH 4 C1) Add the simulated formation water prepared in step (1), add it into the mixer, and fully stir it for 2 minutes at a speed of 8000r / min to obtain the mixture, which is the base liquid;

[0040] (3) Add 1% foaming agent (Ge...

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Abstract

The invention provides a mixed gas foam cracking liquid system and preparation thereof. The mixed gas foam cracking liquid system comprises a gas phase and a liquid phase according to a volume ratio of (2 to 5):1, wherein the gas phase is nitrogen gas; on the basis of 100% of total weight of liquid phase, the liquid comprises the following components in percentage by weight: 0.8 to 1.2% of foamingagent, 0.3 to 0.8% of thickener, 0.8 to 1.2% of foam stabilizer, 45 to 55% of liquid carbon dioxide, and the balance of simulating stratum water. The mixed gas foam cracking liquid system has the advantages that the energy increasing, viscosity increasing, foaming and foam stabilizing functions are integrated, and the mixing advantage of carbon dioxide and nitrogen is fully realized.

Description

technical field [0001] The invention relates to the field of oil exploitation, in particular to a mixed gas foam fracturing fluid system and its preparation. Background technique [0002] The use of foam fracturing has been around for more than 30 years. Foam fracturing began in the 1960s in foreign countries, and the foam fracturing technology gradually matured in the 1970s and 1980s. By the mid-1980s, the foam fracturing technology had developed rapidly. For foam fracturing construction, nitrogen foam fracturing was initially used, and carbon dioxide foam fracturing technology was tried in the early 1980s, which is often used for fracturing operations in medium-deep wells and high-temperature wells under normal pressure. [0003] Nitrogen foam fracturing fluid is used as a medium for creating fractures and carrying sand, and its performance improvement has always been a subject of research. N 2 It is an inert gas and can be compatible with all base fluids (water, brine,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/68C09K8/70
CPCC09K8/68C09K8/703C09K2208/10
Inventor 张劲薛振乾范德元武英俊边万新田庆路周劲辉
Owner CHINA UNIV OF PETROLEUM (BEIJING)
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