Polymer semi-permeable material
A technology of semi-permeable materials and polymers, applied in the field of polymer semi-permeable materials, can solve the problems of easy damage, short service period and high cost of use, and achieve the effects of preventing collapse, long service period and improving durability
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Embodiment 1
[0027] A PTFE material with a three-dimensional penetrating pore structure. There are stem holes on the stems surrounding the pores. The pore diameter is 100-1000nm; the stem diameter is 50-600nm, and the stem pore diameter is 30-200nm; the porosity of the pores is 50%- 90%, the porosity of the stem hole is 15-65%; the total surface area of the stem, stem area:stem hole area=1-30:1.
[0028] Stem surface area image analysis: Photographs of the material were taken with a scanning electron microscope (SEM photographs, 10,000-50,000x magnification). Scan this photo with image processing equipment (the television image processor TVIP-4100II produced by Avionics Corporation of Japan, the television image processor provided by Latock System Engineering Company) separate the stem from the stem hole to obtain the stem and stem hole image, and process the image through software , to obtain the respective areas, the ratio of the stem area to the total area of the stem hole area imag...
Embodiment 2
[0040] The PTFE material of this embodiment has a three-dimensional penetrating pore structure. There are stem holes on the stems surrounding the pores. The pore diameter is 200±100 nm, the stem diameter is 125±75 nm, and the stem hole diameter is 50±20 nm.
[0041] The preparation method of described PTFE material, comprises the following steps:
[0042] (1) Preparation of spinning solution: dissolve polyvinyl alcohol in water to obtain a uniform solution with a concentration of 14-15%, add polytetrafluoroethylene (PTFE) emulsion (55-60%), so that the mass ratio of PTFE to polyvinyl alcohol is 2 -3:1; the preparation of the emulsion is to prepare high molecular polymer particles by emulsion polymerization, and the average particle diameter of the high molecular polymer particles is 15-40nm;
[0043] (2) Spinning: use high-voltage electrospinning equipment for electrospinning to obtain a uniform nanofiber precursor film; spinning voltage 15~20kV, distance 12~30cm;
[0044] (3) ...
Embodiment 3
[0051] The PTFE material of this embodiment has a three-dimensional penetrating pore structure, and there are stem holes on the stems surrounding the pores, 300nm
[0052] Wherein (I) the porosity of the pores is 60±10%, the porosity of the stem pores is 55±10%; the total surface area of the stems, stem area:stem hole area=1-15:1.
[0053] Or (II) the porosity of the pores is 60±10%, and the porosity of the stem pores is 55±10%; the total surface area of the stem, stem area:stem hole area=16-30:1.
[0054] Or (Ⅲ) the porosity of the pores is 80±10%, and the porosity of the stem pores is 30±15%; the total surface area of the stem, stem area:stem hole area=1-15:1.
[0055] Or (IV) The porosity of the pores is 80±10%, and the porosity of the stem pores is 30±15%; the total surface area of the stem, stem area:stem hole area=16-30:1.
[0056] The preparation method of described PTFE material, co...
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