Low-volatility modified polypropylene composite material, preparation method and application thereof

A composite material, low-volatility technology, applied in the field of polymer materials, can solve problems such as the inability to meet the requirements of environmental friendliness of automotive interior trim materials, the difficulty of solving the core layer matrix odor and VOC, and achieve excellent thermal oxygen resistance. Aging performance, mechanical properties do not decline, the effect of reducing odor

Inactive Publication Date: 2019-04-05
TIANJIN KINGFA NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the influence of the above two factors, the odor and VOC of the core matrix are difficult to solve, a

Method used

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  • Low-volatility modified polypropylene composite material, preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] 60kg of low-flow homopolypropylene with a melt flow rate of 3.5g / 10min produced by Yanshan Petrochemical Company, 40kg of medium-flow high-impact polypropylene with a melt flow rate of 10.5g / 10min produced by Qilu Petrochemical Company, and 0.2kg Hindered phenolic antioxidant 1010, 0.3kg phosphite antioxidant 168, 0.3kg lubricant calcium stearate, 0.4kg furnace carbon black M717; add aspect ratio from the main feeding port of the screw extruder 40:1 co-rotating twin-screw extruder, melt blending; 160-200 ° C extrusion granulation, the test results and properties of the composite material obtained in Example 1 are shown in Table 1.

Embodiment 2

[0029] 50kg of low-fluidity polypropylene with a melt flow rate of 3.5g / 10min produced by Daqing Petrochemical Company, 50kg of medium-fluidity high-impact polypropylene with a melt flow rate of 12g / 10min produced by Lanzhou Petrochemical Company, and 1kg of hindered phenolic anti- Oxygen agent 1010, 0.5kg organic thiolipid antioxidant DSTP, 0.5kg lubricant EBS, 0.6kg thermal cracking carbon black N990; from the main feeding port at one end of the screw extruder, the length-to-diameter ratio is 36:1 In the co-rotating twin-screw extruder, carry out melt blending; After melt-blending in the co-rotating twin-screw extruder, 160-200 ℃ extrusion granulation, the test result performance of the composite material obtained in Example 2 is shown in the table 1.

Embodiment 3

[0031] 60kg of low fluidity polypropylene with a melt flow rate of 3.5g / 10min from Fushun Petrochemical, 40kg of medium fluid high impact polypropylene with a melt flow rate of 12g / 10min from Panjin Petrochemical, and 0.7kg of semi-hindered phenolic antioxidant 1790, 0.8kg phosphite antioxidant 168, 0.5kg lubricant monoglyceride stearate GMS, 0.5kg channel carbon black FW200; add the aspect ratio from the main feeding port at one end of the screw extruder Melt blending in a 40:1 co-rotating twin-screw extruder; melt-blending with other components in a co-rotating twin-screw extruder, extruding and granulating at 160-200°C, Example 3 The test results and properties of the obtained composite materials are shown in Table 1.

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Abstract

The invention provides a low-volatility modified polypropylene composite material, a preparation method and an application thereof. The low-volatility modified polypropylene composite material comprises the following components in parts by weight: 35-60 parts of low-flowability polypropylene, 40-60 parts of medium-flowability polypropylene, 0.4-0.8 parts of carbon black, 0-2 parts of an antioxidant, and 0-1 part of a lubricant. The invention provides a low-odor low-volatility environment-friendly product suitable for extrusion rolling production and applied to core layers of a luggage case anda carpet.

Description

technical field [0001] The invention belongs to the field of polymer materials, and in particular relates to a low-volatility modified polypropylene composite material, a preparation method and an application thereof. Background technique [0002] At present, the three-layer composite carpet made of polypropylene material through extrusion calender is mostly used for interior carpet decoration of passenger cars, especially the trunk carpet and the left and right sides of the trunk. This kind of carpet is divided into three layers, the upper and lower layers are polypropylene non-woven felt, and the middle layer is a core layer of polypropylene material, which is mostly modified polypropylene material. Most of these core materials are made of single-extruded low-flow polypropylene materials, and some are made of low-flow modified polypropylene materials made of PP and mineral powder. The melt flow rate of the low-flow high-impact polypropylene material used by many extrusion...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L23/16C08K13/02C08K3/04
CPCC08L23/12C08L2205/025C08L23/16C08K13/02C08K3/04
Inventor 李欣李晟张栋伟张春怀徐昌竹钱文轩张海洋柴新龙陶四平
Owner TIANJIN KINGFA NEW MATERIAL
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