Wear-resistant and oil-resistant engineering sole material and preparation method thereof

A shoe sole material and engineering technology, which is applied in the field of elastomer engineering sole material and its preparation, can solve the problems of difficult dispersion of fillers and auxiliaries, and achieve the effects of solving poor dispersion, reducing wear volume and increasing cross-linking points.

Active Publication Date: 2019-05-31
SOUTH CHINA UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The present invention adopts a two-step mixing method. First, the EVA elastomer system and the oil-resistant rubber system are mixed separately, and then the two are mixed. The two-step mixing method can effectively improve the processing of fillers and additives that ar

Method used

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  • Wear-resistant and oil-resistant engineering sole material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0055] Example 1

[0056] A wear-resistant and oil-resistant engineering shoe sole material, the raw materials of which are composed of:

[0057] EVA 4260: 40 parts

[0058] Nitrile rubber NBR (acrylonitrile content 33%): 60 parts

[0059] nano-SiO 2 : 5 servings

[0060] Carbon black N110: 20 parts

[0061] Si-69: 5 parts

[0062] BIPB: 1.5 copies

[0063] Zinc oxide: 2 parts

[0064] Stearic acid: 0.8 parts

[0065] Zinc stearate: 2.5 parts

[0066] N4016 naphthenic oil: 4 parts

[0067] Antiaging agent RD: 0.5 parts

[0068] A preparation method of a wear-resistant and oil-resistant engineering shoe sole material is as follows:

[0069] Add 40 parts of EVA into the internal mixer, press the top bolt, control the temperature at 80°C, rotate at a speed of 50r / min, and banbury for 50s; then add 0.8 parts of zinc oxide, 0.32 parts of stearic acid, and 1 part of zinc stearate in sequence , Si-69 2 parts, nano-SiO 2 2 parts, 8 parts of carbon black N110, 1.6 parts o...

Example Embodiment

[0072] Example 2

[0073] A wear-resistant and oil-resistant engineering shoe sole material, the raw materials of which are composed of:

[0074] EVA 4260: 70 parts

[0075] Neoprene CR: 30 parts

[0076] nano-SiO 2 : 10 servings

[0077] Carbon black N110: 40 parts

[0078] Si-69: 15 parts

[0079] BIPB: 3 copies

[0080] Zinc oxide: 5 parts

[0081] Stearic acid: 2 parts

[0082] Zinc stearate: 1 part

[0083] N4016 naphthenic oil: 10 parts

[0084] Antiager AW: 2 parts

[0085] A preparation method of a wear-resistant and oil-resistant engineering shoe sole material is as follows:

[0086] Add 70 parts of EVA into the internal mixer, press the top bolt, control the temperature at 80°C, rotate at a speed of 50r / min, and banbury for 50s; then add 3.5 parts of zinc oxide, 1.4 parts of stearic acid, and 0.7 parts of zinc stearate in sequence , Si-69 10.5 parts, nano-SiO 2 7 parts, 28 parts of N110, 7 parts of N4016 naphthenic oil, 1.4 parts of anti-aging agent RD ...

Example Embodiment

[0089] Example 3

[0090] A wear-resistant and oil-resistant engineering shoe sole material, the raw materials of which are composed of:

[0091] EVM 500HV: 50 parts

[0092] Nitrile rubber NBR (acrylonitrile content 42%): 50 parts

[0093] Nano-CaCO 3 : 5 servings

[0094] Carbon black N110: 30 parts

[0095] KH550: 10 parts

[0096] DCP: 2.5 copies

[0097] Zinc oxide: 2.5 parts

[0098] Stearic acid: 1.5 parts

[0099] Zinc stearate: 2 parts

[0100] N4016 naphthenic oil: 8 parts

[0101] Antiager 4020: 1.5 parts

[0102] A preparation method of a wear-resistant and oil-resistant engineering shoe sole material is as follows:

[0103] Add 50 parts of EVM into the internal mixer, press the top bolt, control the temperature at 80°C, rotate at a speed of 55r / min, and banbury for 60s; then add 1.25 parts of zinc oxide, 0.75 parts of stearic acid, and 1 part of zinc stearate in sequence , KH550 5 parts, nano CaCO 3 2.5 parts, 15 parts of N11015, 4 parts of N4016 nap...

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Abstract

The invention discloses a wear-resistant and oil-resistant engineering sole material and a preparation method thereof. The wear-resistant and oil-resistant engineering sole material comprises, by weight, 40-70 parts of ethylene-vinyl acetate copolymer, 30-60 parts of synthetic rubber, 4.5-10.5 parts of nano filler, 18-45 parts of reinforcing agent, 5-15.5 parts of coupling agent, 1.4-3.4 parts ofcrosslinking agent, 2-5.5 parts of zinc oxide, 0.8-2.3 parts of stearic acid, 1-2.5 parts of zinc stearate, 4-11 parts of naphthenic oil and 0.5-2.2 parts of anti-aging agent. The wear-resistant and oil-resistant engineering sole material has the advantages that the oil-resistant mass change rate of the sole material reaches 5.1-8.8%, the volume change rate of the sole material reaches 9.1-11.8%,the DIN abrasion volume of the sole material reaches 54-82mm<3>, and the volume resistivity of the sole material reaches 10<6>-10<8> ohm*m; meanwhile, the sole material is excellent in mechanical performance, good in elasticity, good in damping performance and suitable for being used for producing soles used in working environments such as oil fields and kitchens.

Description

technical field [0001] The invention relates to an elastomer engineering shoe sole material and a preparation method thereof, in particular to an engineering shoe sole material with excellent wear resistance and oil resistance, good antistatic performance and mechanical properties and a preparation method thereof. Background technique [0002] Traditional sole materials usually adopt rubber (elastomer), which has the advantages of light weight, good elasticity, non-slip, waterproof, and shock absorption. Ethylene-vinyl acetate copolymer (EVA) is an elastomer material widely used in the field of shoe materials. According to the content of vinyl acetate monomer (VA), it can be made into sports shoe soles for different purposes, but EVA soles are wear-resistant , poor oil resistance, which restricts the development of EVA soles in the field of engineering shoe materials that need wear-resistant and oil-resistant working environments such as oil fields, chemicals, construction, ...

Claims

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Application Information

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IPC IPC(8): C08L23/08C08L9/02C08L11/00C08L91/00C08K13/02C08K3/36C08K3/34C08K3/26C08K3/04C08K3/22C08K5/09C08K5/098C08J3/24A43B13/04
Inventor 何慧冯宇超王炳程
Owner SOUTH CHINA UNIV OF TECH
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