A kind of aldehyde-free flour-based adhesive and preparation method thereof

A flour and glue-based technology, applied in adhesives, adhesive additives, non-polymer adhesive additives, etc., can solve problems such as poor water resistance bonding performance, environmental pollution of human settlements, free formaldehyde release, etc., to achieve enhanced glue Good bonding performance, improved cross-linking density, and good uniformity

Active Publication Date: 2021-02-02
山东千森木业集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] With the improvement of people's living standards, the pollution of human settlements has attracted attention. The use of biomass adhesives to prepare wood-based panels can solve the problem of free formaldehyde release from wood-based panels. It is an important way to solve the problem, but most biomass adhesives There is the problem of poor water-resistant adhesive performance of the agent, which limits its industrial application

Method used

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  • A kind of aldehyde-free flour-based adhesive and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0035] This embodiment provides a preparation method of flour adhesive, and the adhesive is prepared according to the following weight ratio:

[0036] Modified flour 38 kg

[0037] Surface modified attapulgite 0.4 kg

[0038] Polyacrylamide 0.1kg

[0039] Self-made multifunctional epoxy compound 8kg

[0040] Sodium hydroxide solution 0.5kg

[0041] This embodiment also provides the preparation method of the above-mentioned adhesive, and the specific preparation steps are as follows:

[0042] (1) Weigh the components according to the weight ratio, add the surface-modified attapulgite to the dispersion medium water, ultrasonicate for 15 minutes, and then add half the weight of modified flour, use a high-pressure homogenizer, under 30MPa pressure and 0.5MPa Under the action of emulsifying force, homogeneously emulsify for 20 minutes;

[0043] (2) Add the remaining modified flour to the mixture obtained in step (1), mix well, add self-made multifunctional epoxy compound and t...

Embodiment 2

[0045] This embodiment provides a preparation method of flour adhesive, and the adhesive is prepared according to the following weight ratio:

[0046] Modified flour 42kg

[0047] Surface modified attapulgite 0.8 kg

[0048]Polyacrylamide 0.3kg

[0049] Self-made multifunctional epoxy compound 12kg

[0050] Sodium hydroxide solution 1.0kg

[0051] The preparation method of the adhesive described in this embodiment is the same as that in Example 1.

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Abstract

The invention discloses an aldehyde-free flour-based adhesive and a preparation method thereof. 0.1-0.3 parts by weight of the regulator, 8-12 parts by weight of the crosslinking agent, and 0.5-1 parts by weight of the catalyst; prepared by the following method: weighing each component according to the weight ratio, adding the reinforcing agent to the dispersion medium water, and ultrasonicating for 15 minutes , and then add half the weight of the main agent, use a high-pressure homogenizer, under the action of 30MPa pressure and 0.5MPa emulsifying force, homogeneously emulsify for 20 minutes; add the remaining main agent to the mixture obtained above, mix well and then add cross-linking The adhesive and the remaining catalyst were reacted at 80°C for 30 minutes, and the material was discharged at a temperature of 30°C; the adhesive of the present invention is easy to form a cross-linked structure, has a high cross-linking density, a low reaction temperature, a simple preparation method, and the prepared adhesive has stable performance and weak interface. Significant drop in ply, lower cost, good dry / wet strength, and stable improvement in product quality.

Description

technical field [0001] The invention relates to the field of plywood preparation, in particular to an aldehyde-free flour-based adhesive and a preparation method thereof. Background technique [0002] my country's precious wood resources are relatively scarce, and artificial forest resources are abundant. Using artificial forest fast-growing wood to prepare wood-based panels through adhesives is the main raw material for furniture floors and interior decoration in the living environment. In 2017, the total output of my country's wood-based panels was 295 million cubic meters Rice, accounting for about 50% of the world's total output, of which more than 60% are plywood products. Based on the average production of 9 cubic meters of wood-based panels per ton of adhesive, the consumption of adhesives for plywood in my country in 2017 was about 18 million tons (solid content 50%), of which urea-formaldehyde resin and its modified products accounted for the total output of adhesive...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J199/00C09J11/04C09J11/06
CPCC08K2201/011C09J11/04C09J11/06C09J199/00C08L33/26C08K9/04C08K3/346
Inventor 高强张一张婕妤李建章周文瑞张伟
Owner 山东千森木业集团有限公司
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