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Long-acting antistatic composite chinlon fabric and preparation method thereof

An anti-static and nylon technology, applied in the manufacture of conductive/anti-static filaments, single-component polyamide artificial filaments, etc., can solve the problem that the conductivity of composite powders is difficult to guarantee, the aggregation of carbon materials cannot be avoided, and spinning cannot be performed Handling and other issues, to achieve the effect of helping interface charge transfer, facilitating continuous preparation, and easy charge transfer

Active Publication Date: 2019-10-08
HANGZHOU GAOXI TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

CN103832997A "A graphene / carbon black composite material and its preparation method and application" uses graphite oxide and carbon black compounding method to prepare conductive composite powder, but the preparation is complicated, the cost is high, and the industrialization is difficult
CN107516740A "A Composite Conductive Agent of Rock Black and Graphene Powder and Its Preparation" adopts the method of adding carbon black to the preparation process of graphite oxide to obtain a composite conductive agent, but the oxidant of graphite oxide itself may damage the structure of carbon black, and the composite powder The electrical conductivity is difficult to guarantee
CN106147185 "Conductive polycarbonate-based pellets containing multidimensional carbon nanomaterials, its preparation method and application" blends carbon black, graphene and carbon nanotubes with polycarbonate to realize the multidimensional carbon materials to form a conductive network together purpose, but this method cannot avoid the aggregation of carbon materials and cannot be used for spinning

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Long-acting antistatic composite chinlon fabric and preparation method thereof
  • Long-acting antistatic composite chinlon fabric and preparation method thereof
  • Long-acting antistatic composite chinlon fabric and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] (1) Add 5 parts by mass of an aqueous dispersion of modified graphene and 0.05 parts by mass of a molecular weight regulator into 100 parts by mass of caprolactam melt, and stir and mix at 300 rpm at 80° C. to form a dispersion. The modified graphene is a single-layer graphene with oxygen-containing functional groups such as carboxyl and hydroxyl groups on the surface, the carbon-to-oxygen ratio is 2.5, and the mass concentration of the modified graphene aqueous dispersion is 1%;

[0030](2) 0.3 parts of high DBP value nano-carbon black and 1.2 parts of low DBP value nano-carbon black are mixed and added to the mixed solution obtained in step (1), and high-speed shear dispersion is carried out by an emulsifying homogenizer at 80 ° C; wherein The DBP value of nano carbon black with high DBP value is 360, and the DBP value of carbon black with low DBP value is 240;

[0031] (3) Under nitrogen protection, heat up the dispersion liquid obtained in step (2) to 250°C in a pol...

Embodiment 2

[0037] (1) Add 5 parts by mass of an aqueous dispersion of modified graphene and 0.05 parts by mass of a molecular weight regulator into 100 parts by mass of caprolactam melt, and stir and mix at 500 rpm at 80° C. to form a dispersion. The modified graphene is a single-layer graphene with oxygen-containing functional groups such as carboxyl and hydroxyl groups on the surface, the carbon-to-oxygen ratio is 6, and the mass concentration of the modified graphene water dispersion is 3%;

[0038] (2) 0.3 parts of high DBP value nano-carbon black and 1.5 parts of low DBP value nano-carbon black are mixed and added to the mixed solution obtained in step (1), and high-speed shear dispersion is carried out by an emulsifying homogenizer at 80 ° C; wherein The DBP value of nano carbon black with high DBP value is 400, and the DBP value of carbon black with low DBP value is 240;

[0039] (3) Under the protection of nitrogen, the dispersion obtained in step (2) was heated to 260°C in a pol...

Embodiment 3

[0045] (1) Add 5 parts by mass of an aqueous dispersion of modified graphene and 0.3 parts by mass of a molecular weight regulator into 100 parts by mass of caprolactam melt, and stir and mix at 500 rpm at 80° C. to form a dispersion. The modified graphene is a single-layer graphene with oxygen-containing functional groups such as carboxyl and hydroxyl groups on the surface, the carbon-to-oxygen ratio is 4, and the mass concentration of the modified graphene aqueous dispersion is 6%;

[0046] (2) 0.3 parts of high DBP value nano-carbon black and 1.2 parts of low DBP value nano-carbon black are mixed and added to the mixed solution obtained in step (1), and high-speed shear dispersion is carried out by an emulsifying homogenizer at 80 ° C; wherein The DBP value of nano carbon black with high DBP value is 380, and the DBP value of carbon black with low DBP value is 280;

[0047] (3) Under the protection of nitrogen, the dispersion obtained in step (2) was heated to 270°C in a po...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention discloses a long-acting antistatic composite chinlon fabric and a preparation method thereof. A novel nano composite structure is formed by compounding carbon black with a specific DBP value with single-layer modified graphene in a specific proportion, and a conductive adding material with excellent dispersibility is obtained. The conductive adding material and caprolactam are subjected to in-situ copolymerization, melt spinning and weaving to prepare the long-acting antistatic composite chinlon fibers. According to the invention, only a small amount of graphene and a small amount of carbon black are added, traditional chinlon has excellent antistatic effect, the spinnability of the product is good, the performance is stable, the cost is low, the industrialization difficultyis small, and the long-acting antistatic composite chinlon fabric has obvious practical value.

Description

technical field [0001] The invention belongs to the field of chemical fiber fabrics, in particular to a long-acting antistatic composite nylon fabric and a preparation method thereof. Background technique [0002] In daily life, when two objects of different materials are in contact and then separated, static electricity can be generated. This is because one object loses a certain amount of charge and becomes positively charged, while the other object gains charge and becomes negatively charged. These charges are difficult to neutralize easily. It will gradually accumulate to form static electricity. The main ways to form static electricity in daily life are friction, induction and conduction. Static electricity itself is a very common phenomenon, but when the static electricity is accumulated and released violently, it is very easy to cause circuit breakdown, information interference, fire, electric shock and other phenomena, which can cause discomfort to the human body, i...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F1/09D01F6/90C08G69/16
CPCC08G69/16D01F1/09D01F6/90
Inventor 陈琛韩燚高超
Owner HANGZHOU GAOXI TECH CO LTD
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