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A kind of aldehyde-free low-cost polysaccharide adhesive and preparation method thereof

A low-cost, polysaccharide glue technology, applied in polysaccharide adhesives, adhesives, adhesive additives, etc., can solve the problems of poor water-resistant bonding performance, achieve enhanced bonding performance, improve bonding stability, and improve distribution uniformity Effect

Active Publication Date: 2021-04-30
BEIJING FORESTRY UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] As people pay more attention to the health of the living environment, the use of biomass adhesives to fundamentally solve the problem of free formaldehyde release from wood-based panels has attracted much attention. However, most biomass adhesives have the problem of poor water resistance and bonding performance, which limits its industrial application

Method used

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  • A kind of aldehyde-free low-cost polysaccharide adhesive and preparation method thereof

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preparation example Construction

[0054] A method for preparing an aldehyde-free and low-cost polysaccharide adhesive, characterized in that it comprises the following steps:

[0055] (1) Weigh each component according to the weight ratio, mix the nanofibers grafted with methylolmelamine and dispersion medium water, and ultrasonically disperse for 15 minutes;

[0056] (2) Add the hyperbranched amino polysaccharide to the solution of (1), pass the mixed solution through a high-pressure homogenizer, and homogenize for 15 minutes under a pressure of 70 MPa;

[0057] (3) Add multifunctional epoxy compound and polyacrylamide to the mixture obtained in step (2) successively, and stir evenly.

Embodiment 1

[0059] This embodiment provides a preparation method of a polysaccharide adhesive, and the adhesive is prepared according to the following weight ratio:

[0060] Hyperbranched amino polysaccharides 20 kg

[0061] Multifunctional epoxy compound 6 kg

[0062] Nanofibers grafted with methylol melamine 1 kg

[0063] Polyacrylamide 1 kg

[0064] This embodiment also provides the preparation method of the above-mentioned adhesive, and the specific preparation steps are the same as the above-mentioned preparation method.

Embodiment 2

[0066] This embodiment provides a preparation method of a polysaccharide adhesive, and the adhesive is prepared according to the following weight ratio:

[0067] Hyperbranched Glycan 25 kg

[0068] Multifunctional epoxy compound 16 kg

[0069] Nanofibers grafted with methylolmelamine 2 kg

[0070] Polyacrylamide 3 kg

[0071] The preparation method of the adhesive described in this embodiment is the same as that in Example 1.

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Abstract

The invention discloses an aldehyde-free and low-cost polysaccharide adhesive and a preparation method thereof, comprising the following components by weight: 20-25 parts by weight of main agent, 55-60 parts by weight of dispersion medium water, and 6-16 parts by weight of crosslinking agent Parts by weight, 1-2 parts by weight of reinforcing agent, 1-3 parts by weight of viscosity regulator; its preparation method of polysaccharide-based adhesive comprises the steps of: first weighing each component according to the weight ratio, and mixing the reinforcing agent with the dispersion medium Mix with water and ultrasonically disperse for 15 minutes; then add the main ingredient to the above-prepared solution, pass the mixed solution through a high-pressure homogenizer, and homogenize it for 15 minutes under a pressure of 70 MPa; finally add the crosslinking agent and viscosity regulator successively In the mixture obtained in the second step, stir evenly; the adhesive prepared by the simple preparation method of the present invention has the advantages of high crosslinking density, good water resistance, high dry and wet strength, adjustable viscosity, and low curing temperature. It has met the practical requirements of plywood adhesives, has low production cost, simple preparation process, and can be mass-produced on a large scale, which will help promote the development of the green high-performance adhesive industry.

Description

technical field [0001] The invention relates to the field of plywood preparation, in particular to an aldehyde-free and low-cost polysaccharide adhesive and a preparation method thereof. Background technique [0002] my country's wood-based panel production accounts for half of the world's total output, and it is the main source of furniture, flooring, and interior decoration materials. Every year, my country's plywood manufacturing consumes about 18 million tons of urea-formaldehyde resin and its modified product adhesives (solid content 50%), accounting for The total output of agent is more than 90%. Urea-formaldehyde resin adhesives have the problem of formaldehyde release from products. [0003] As people pay more attention to the health of the living environment, the use of biomass adhesives to fundamentally solve the problem of free formaldehyde release from wood-based panels has attracted much attention. However, most biomass adhesives have the problem of poor water r...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J105/00C09J133/26C09J101/02C09J11/08C08B37/00C08B15/06
CPCC08B15/06C08B37/006C08L2205/03C09J11/08C09J105/00C08L33/26C08L1/02
Inventor 张一高强李建章徐业程周文瑞龚珊珊
Owner BEIJING FORESTRY UNIVERSITY
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