The invention belongs to the technical field of functional adhesives, and relates to a preparation method and application of an ultra-long room-temperature phosphorescent
formaldehyde-free
adhesive. The method comprises the following steps: by taking
lignin as a basic component, sequentially reacting with
epichlorohydrin and an
amination reagent under an alkaline condition to obtain ammoniated modified
lignin; meanwhile, dispersing a natural polyhydroxy
polymer in water, performing light oxidation treatment, and embedding a phosphorescent light-emitting unit through a
covalent bond to obtain a functional cross-linking agent; and finally, uniformly mixing the two products at
room temperature to prepare the ultra-long room-temperature phosphorescent
formaldehyde-free
adhesive. According to the method,
biomass molecules are taken as a main body of raw materials, the
process conditions are mild, and the obtained
adhesive forms a
covalent bond and
hydrogen bond dual rigid network after being heated and fully cured, so that the adhesive can reflect the ultra-long room-temperature
phosphorescence characteristic under the excitation of
ultraviolet light, has the functions of
interface bonding and optical recognition, and can be applied to the field of light emitting devices. The method can be applied to anti-counterfeiting and tracing of wood composite materials and related interface systems.