Nutrient fertilizer for improving black tea quality and high-efficiency nutrient management method
A technology for nutrients and black tea, applied in fertilization methods, fertilizer mixtures, ammonium orthophosphate fertilizers, etc., can solve the problems of short aging, poor effect, easy pollution, etc., and achieve the effects of long aging, stable chemical structure, and not easy to pollute.
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Embodiment 1
[0031] Embodiment 1 Synthesis of novel nitrification inhibitor
[0032] synthetic route:
[0033]
[0034] Synthesis method: Dissolve 2 mol of acrylic acid and 1 mol of itaconic acid in 100 mL of water, heat up to 70°C, add 10 mL of 5wt% hydrogen peroxide and 20 mL of 6wt% sodium hypophosphite solution dropwise at the same time, control the dropping speed, and finish dropping within 30 minutes. In the process of adding the solution, control the difference of the reaction temperature not to be higher than 1°C. After the dropwise addition, continue to raise the reaction temperature to the reflux state. After reacting for 2 hours, cool to room temperature to obtain the acrylic acid / itaconic acid copolymer.
Embodiment 2
[0035] Example 2 Synthesis of novel nitrification inhibitors
[0036] synthetic route:
[0037]
[0038]Synthesis method: Dissolve 1mol of acrylic acid and 2mol of itaconic acid in 100mL of water, heat up to 95°C, add 10mL of 10wt% hydrogen peroxide and 20mL of 10wt% sodium hypophosphite solution dropwise at the same time, control the dropping speed, finish the dropping within 50min, drop In the process of adding the solution, control the difference of the reaction temperature to not be higher than 1°C. After the dropwise addition, continue to raise the reaction temperature to the reflux state. After reacting for 5 hours, cool to room temperature to obtain the acrylic acid / itaconic acid copolymer.
Embodiment 3
[0039] Example 3 Synthesis of novel nitrification inhibitors
[0040] synthetic route:
[0041]
[0042] Synthesis method: Dissolve 1 mol of acrylic acid and 1 mol of itaconic acid in 100 mL of water, heat up to 85°C, and simultaneously add 10 mL of 7wt% hydrogen peroxide and 20 mL of 8wt% sodium hypophosphite solution dropwise. During the process of adding the solution, control the reaction temperature difference not to be higher than 1°C. After the dropwise addition, continue to raise the reaction temperature to reflux state. After reacting for 3 hours, cool to room temperature to obtain an acrylic acid / itaconic acid copolymer.
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