Aerogel fire extinguishing agent and preparation method thereof
An airgel and fire extinguishing agent technology, applied in fire prevention equipment, chemical instruments and methods, inorganic chemistry, etc., can solve the problems of difficult uniform dispersion and poor synergistic effect of fire extinguishing enhancers, so as to achieve high fire extinguishing efficiency and prevent ignition good effect
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[0026] Silica airgel was prepared according to the following method: the sodium silicate solution was adjusted to pH ≥ 9 by adding 2M sulfuric acid solution dropwise until the gel phenomenon occurred, aged at 55°C for 24 hours; washed 3 times with water, and then placed in absolute ethanol Carry out solvent replacement, the mass ratio of anhydrous ethanol to sodium silicate is 5:1; after suction filtration, dry under normal pressure, dry by programmed temperature rise, and finally cool naturally. The temperature programming mechanism is 80°C / 2h+100°C / 2h+120°C / 2h; the heating rate is 2°C / min.
[0027] The average pore diameter of the silica airgel is 28nm; the density is 0.043g / cm3; the thermal conductivity is 0.018W / (mK).
[0028] Silica airgel is added into the polyethyleneimine aqueous solution of pH=5 to disperse evenly, obtains modified silica airgel solution; The number average molecular weight Mn=1800 of described polyethyleneimine; The amine value is 19mmol / g; primary...
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