c, al double element injection method for preparing low-friction fluorosilicone rubber surface

A fluorosilicone rubber and low-friction technology, which is applied in the field of polymer surface modification, can solve problems such as low mechanical strength and complicated reinforcement process, and achieve the effects of improved mechanical strength, strong controllability, and simple operation

Active Publication Date: 2021-07-23
LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, FVMQ faces the problems of low mechanical strength and complicated reinforcement process in application. Therefore, improving and increasing the strength of fluorosilicone rubber is also an important research topic.

Method used

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  • c, al double element injection method for preparing low-friction fluorosilicone rubber surface

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] (1) Grind the FVMQ with fine sandpaper to remove surface pollutants and obtain a smooth sample, then place it in soapy water at 45 °C with a small brush for further cleaning; then put it into deionized water heated to about 80 °C for ultrasonic cleaning for 8 minutes, Repeat 5 times to remove residual soap and pollutants on the surface; after cleaning, put FVMQ in an oven, dry at 85 °C for 30 min, and cool to room temperature for later use;

[0022] (2) Put the processed FVMQ into the vacuum chamber, and evacuate to 1×10 -4 Pa (C target and Al target are pre-installed in the vacuum chamber as ion implantation materials);

[0023] (3) Turn on the arc power supply, adjust the C target current to 43 A, the duty cycle to 40%, and generate a beam current density of 0.43 A / 100 cm 2 s; control accelerating voltage -25 kV, rated current 90A, frequency 3 kHz, using Mevva-5 Ru vacuum arc ion source to inject C for 230s;

[0024] (4) Turn off the C target and open the Al target...

Embodiment 2

[0028] (1) Cleaning of FVMQ: same as Example 1;

[0029] (2) Put the processed FVMQ into the vacuum chamber, and evacuate to 1×10 -4 Pa (C target and Al target are pre-installed in the vacuum chamber as ion implantation materials);

[0030] (3) Turn on the arc power supply, adjust the C target current to 35 A, the duty cycle to 40%, and generate a beam current density of 0.35 A / 100cm 2 s; control accelerating voltage -25 kV, rated current 90 A, frequency 5 kHz, and inject C with Mevva-5 Ru vacuum arc ion source for 300 s;

[0031] (4) Turn off the C target and open the Al target at the same time, adjust the Al target current to 35 A, the duty cycle to 60%, and generate a beam current density of 0.35 A / 100cm 2 s;

[0032] (5) Keep the accelerating voltage -25 kV, rated current 90 A, frequency 5 kHz, use Mevva-5·Ru vacuum arc ion source to inject Al for 360 s, and take it out after the cavity is cooled to obtain the modified FVMQ;

[0033] (6) The friction performance of t...

Embodiment 3

[0035] (1) cleaning treatment FVMQ is the same as embodiment 1;

[0036] (2) Put the processed FVMQ into the vacuum chamber, and evacuate to 1×10 -4 Pa (C target and Al target are pre-installed in the vacuum chamber as ion implantation materials);

[0037] (3) Turn on the arc power supply, adjust the C target current to 50 A, the duty cycle to 40%, and generate a beam current density of 0.50 A / 100cm 2 s; control accelerating voltage -25 kV, rated current 90 A, frequency 1 kHz, inject C with Mevva-5 Ru vacuum arc ion source for 100 s;

[0038] (4) Turn off the C target and open the Al target at the same time, adjust the Al target current to 50 A, the duty cycle to 60%, and generate a beam current density of 0.50A / 100cm 2 s;

[0039] (5) Keeping the accelerating voltage at -25 kV, rated current at 90 A, and frequency at 1 kHz, Al was implanted with Mevva-5 Ru vacuum arc ion source for 120 s; after the cavity was cooled, it was taken out to obtain modified FVMQ;

[0040] (6)...

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Abstract

The invention discloses a method for preparing the surface of low-friction fluorosilicone rubber by double-element injection of C and Al. A vacuum arc ion source is used to sequentially inject C and Al on the surface of fluorosilicone rubber to obtain low-friction fluorosilicone rubber with improved mechanical strength. , The friction coefficient of fluorosilicone rubber is reduced from 0.8 to about 0.25. The present invention can effectively improve the mechanical strength, oil resistance and swelling property of FVMQ due to the incorporation of C element in fluorosilicone rubber; the incorporation of Al element can reduce the friction coefficient of FVMQ and obtain low-friction reinforcement FVMQ. For industrial applications, The present invention has great significance. In addition, the present invention uses the Mevva‑5.Ru vacuum arc ion source to perform sequential implantation of dual elements (C and Al) on the surface of the FVMQ, which is simple to operate and highly controllable.

Description

technical field [0001] The invention relates to a method for surface modification to reduce the surface friction coefficient of fluorosilicone rubber, in particular to a method for preparing a low-friction fluorosilicone rubber surface by injecting C and Al dual elements, which belongs to the field of polymer surface modification. Background technique [0002] Fluorosilicone rubber (FVMQ) is a colorless, transparent, high-viscosity plastic linear polymer compound. It is a linear polymer composed of soft Si-O as the main chain. The side groups connected to silicon are methyl, Vinyl and trifluoropropyl, molecular weight between 500,000 and 800,000. On the basis of maintaining the heat resistance, cold resistance, high voltage resistance, and weathering resistance of silicone materials, FVMQ also has excellent resistance to aviation fuel oil, hydraulic oil, and engine oil due to the introduction of fluorine-containing groups. , chemical reagents and solvents and other properti...

Claims

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Application Information

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Patent Type & AuthorityPatents(China)
IPC IPC(8): C23C14/48C23C14/06C23C14/20C08J7/12
CPCC08J7/12C08J2383/08C23C14/0605C23C14/20C23C14/48
Inventor张斌贾倩张俊彦杨生荣王宏刚
OwnerLANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI