Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Process for synthesizing anode material of lithium ion cell

A technology for lithium-ion batteries and positive electrode materials, which is applied in the field of synthetic lithium-ion battery positive electrode materials, can solve problems such as waste of water resources, environmental pollution, and environmental pollution, and achieve the effects of saving water and reducing costs

Inactive Publication Date: 2006-10-25
SHANDONG UNIV OF SCI & TECH
View PDF0 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Generally speaking, the synthesis of positive electrode materials needs to add sodium hydroxide solution to the soluble salt solution to react to form precipitates, which often have harmful metal sodium ions attached to them. In order to remove these metal ions, it will take more than three times. Washing with water to remove useless metal ions, these lotions are generally discharged into the environment, causing pollution to the environment
It wastes water resources and pollutes the environment

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Example 1: At room temperature, a certain amount of cobalt nitrate and lithium hydroxide are dissolved in water respectively to form a solution with a concentration of 3mol / L, and the two solutions are uniformly mixed and reacted until the two solutions react completely and no longer continue to generate Until the cobalt hydroxide precipitates; the mixture of the cobalt hydroxide precipitate and lithium nitrate aqueous solution formed by the reaction is filtered to form a filter cake, and the filter cake is dried to measure the lithium ion content therein. Mix the dried lithium-containing filter cake with a certain amount of lithium carbonate, and the amount of lithium carbonate added is carried out according to the ratio of the number of cobalt and lithium ions to 1:1 (the lithium ions also include those adsorbed on the filter cake. Lithium ions), and then fired at a constant temperature of 900°C for 1.5h to synthesize lithium cobaltate.

[0015] The molecular formula ...

Embodiment 2

[0016] Embodiment 2: at 50 ℃, at first a certain amount of cobalt nitrate, the mixture of manganese nitrate and nickel nitrate (wherein cobalt ion, manganese ion, nickel ion ratio are 1: 1: 1) and lithium hydroxide are dissolved in water respectively ( The solution concentration is 3mol / L), the lithium hydroxide solution and the mixture solution are uniformly mixed and reacted until the complete reaction of the two solutions does not continue to generate hydroxide (cobalt hydroxide, manganese hydroxide, nickel hydroxide) precipitation; Filter the mixture of hydroxide precipitate and lithium nitrate aqueous solution to form a filter cake, dry the filter cake, and measure the lithium ion content therein. Mix the dried lithium-containing filter cake with a certain amount of lithium carbonate, and mix according to the ratio of cobalt+manganese+nickel ions: lithium ions at a ratio of 1:1.02 (the lithium ions also include those adsorbed on the filter cake. Lithium ions), and then fi...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The process of synthesizing positive electrode material for lithium ion cell includes the following steps: adding lithium hydroxide aqua homogeneously into soluble salt solution to generate hydroxide precipitate and lithium salt solution until no further reaction; filtering the reaction product to obtain hydroxide filter cake with adsorbed lithium ion; stoving the filter cake and measuring the lithium content in the filter cake; mixing lithium salt in certain amount with stoved filter cake homogeneously and backing at constant temperature for certain time to obtain the positive electrode material for lithium ion cell of molecular expression of Li1+xMO2, with x having the range of -0.1 to +0.2. The present invention uses lithium hydroxide, rather than sodium hydroxide, and there is no need of water washing to eliminate lithium ion attached to the precipitate, resulting in saving in water and lowered cost.

Description

technical field [0001] The invention relates to a method for synthesizing positive electrode materials of lithium ion batteries. Background technique [0002] As a green high-energy power source, lithium ion has been widely valued for more than ten years. It has the characteristics of high energy, good cycle performance and low self-discharge. In order to give full play to the performance characteristics of lithium-ion batteries, researchers around the world are actively studying lithium-ion batteries. Generally speaking, the synthesis of positive electrode materials needs to add sodium hydroxide solution to the soluble salt solution to react to form a precipitate, which often has harmful metal sodium ions attached to it. In order to remove these metal ions, it will take more than three times. Washing with water to remove useless metal ions, these lotions are generally discharged into the environment, causing pollution to the environment. Not only wasting water resources b...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/04H01M4/48H01M4/58C01D15/00C01G1/02C01G45/00C01G51/00C01G53/00H01M4/50H01M4/52H01M10/36
CPCH01M4/505H01M4/525H01M10/0525Y02E60/10
Inventor 谷亦杰
Owner SHANDONG UNIV OF SCI & TECH
Features
  • Generate Ideas
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More