Method for extracting metal copper using microbe and its use
A technology for extracting metals and microorganisms, applied to the improvement of process efficiency, photography technology, instruments, etc., can solve the problems of no recycling, waste, etc., and achieve the effect of low cost, effective recovery, and high-efficiency leaching
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Embodiment 1
[0045] (1) Pulverize the printed circuit board from which components have been removed into 40 mesh powder;
[0046] (2) Put the printed circuit board powder into the cultivated Thiobacillus ferrooxidans culture solution B1 by 10g / L;
[0047] (NH 4 ) 2 SO 4
KCl
K 2 HPO 4
MgSO 4 ·7H 2 o
Ca(NO 3 ) 2
FeSO 4 ·7H 2 o
h 2 o
Medium B1
3.0g
0.2g
0.5g
0.5g
0.01g
45.0g
1L
[0048] The pH of the culture medium B1 is 2.0, with H 2 SO 4 adjust.
[0049] The concentration of Thiobacillus ferrooxidans in culture medium B1 containing Thiobacillus ferrooxidans reaches 10 7 Individuals / mL order of magnitude or more.
[0050] (3) The mixing method of stirring and aeration is used for leaching for 15 days, and the leaching efficiency can reach 100%;
[0051] (4) Separating the leached solid and liquid, taking the leachate, and carrying out three-stage extraction with the extractant P204, ...
Embodiment 2
[0055] (1) Pulverize the printed circuit board from which components have been removed into 80-mesh powder;
[0056] (2) Putting the printed circuit board powder into the cultivated microspiral culture medium B2 containing ferrous oxide by 20g / L;
[0057] (NH 4 ) 2 SO 4
KCl
K 2 HPO 4
MgSO 4 ·7H 2 o
Ca(NO 3 ) 2
FeSO 4 ·7H 2 o
h 2 o
Medium B2
0.2g
0.1g
0.1g
0.5g
0.01g
10g
1L
[0058] The pH of the culture medium B2 is 2.5, with H 2 SO 4 adjust.
[0059] The ferrous oxidative microspiral concentration in the cultivated ferrous oxidative microspiral culture solution reached 10 8 Individuals / mL order of magnitude or more.
[0060] (3) The mixing method of stirring and aeration is used for leaching for 20 days, and the leaching efficiency can reach 98%;
[0061] (4) Separating the leached solid and liquid, taking the leachate, and carrying out three-stage extraction with the...
Embodiment 3
[0065] (1) The printed circuit board with the components removed is broken into 80 mesh powder;
[0066] (2) Putting the printed circuit board powder into the cultivated Thiobacillus ferrooxidans culture medium B2 by 50g / L;
[0067] (NH 4 ) 2 SO 4
KCl
K 2 HPO 4
MgSO 4 ·7H 2 o
Ca(NO 3 ) 2
FeSO 4 ·7H 2 o
h 2 o
Medium B2
0.15g
0.05g
0.05g
1.0g
0.1g
25g
1L
[0068] The pH of the culture medium B2 is 1.5, with H 2 SO 4 adjust.
[0069] The concentration of Thiobacillus ferrooxidans in the cultivated culture solution containing Thiobacillus ferrooxidans reaches 10 7 Individuals / mL order of magnitude or more.
[0070] (3) The mixing method of stirring and aeration is used for leaching for 30 days, and the leaching efficiency can reach 97%;
[0071] (4) Separating the leached solid and liquid, taking the leachate, and carrying out three-stage extraction with the extractant P20...
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