Polyolefin drag reducing agents produced by non-cryogenic grinding

A drag reducer, alpha olefin technology, applied in the field of polymer drag reducers in particle form

Active Publication Date: 2014-09-10
BAKER HUGHES INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, none of these existing methods has proven to be fully satisfactory

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-4

[0029] Polyolefin polymers are ground into DRA granules in a dual pass process, passing through two processors or mills one after the other, wherein the impeller of the first processor is semi-open, and the impeller of the second processor is The impeller type is closed. yielded the following data:

[0030] Example #1

[0031] Particle size (mv) 259 microns

[0032] Particle size (D95) 493 microns

[0033] Example #2

[0034] Particle size (mv) 197 microns

[0035] Particle size (D95) 360 microns

[0036] Example #3

[0037] Particle size (mv) 268 microns

[0038] Particle size (D95) 497 microns

[0039] Example #4

[0040] Particle size (mv) 249 microns

[0041] Particle size (D95) 425 microns

[0042] "MV" refers to the mean diameter of the volume distribution and represents the center and center of gravity of the particle size distribution curve. The particle size given first is the final particle size after the second process, where "D95" means that about 95% o...

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PUM

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Abstract

Fine particulate polymeric drag reducing agents (DRA) with bimodal or multimodal particle size distributions can be produced simply and efficiently without cryogenic temperatures. Polymers such as poly(alpha-olefins) can be ground or pulverized to suit reduced drag in flowing hydrocarbons by using at least one liquid grinding aid and at least two grinding processors in series. The impellers of the grinders have different openings to grind the granular polymer to an intermediate size when added to a first processor with a more open impeller and to a second processor with a relatively more closed impeller. , the processor grinds the polymer into a second, smaller size. Non-limiting examples of suitable liquid grinding aids include blends of propylene glycol, water and hexanol. Particle DRA with a size of about 300 microns or less can be produced in just two processes.

Description

technical field [0001] This invention relates to a method of producing polymeric drag reducers in the form of finely divided particles, and most particularly to grinding polymeric drag reducers in two or more processes that do not require grinding at cryogenic temperatures to produce their fine particle method. Background technique [0002] The use of poly-alphaolefins or copolymers thereof to reduce the resistance of hydrocarbons to flow through pipelines, and thereby reduce the energy requirements for the transport of such fluid hydrocarbons, is well known. In the past, these drag reducing agents, or DRAs, have taken various forms, including slurries or dispersions of ground polymers to form free-flowing and pumpable mixtures in liquid media. The problem commonly experienced with simply grinding polyalphaolefin (PAO) is that over time the particles can "cold flow" or stick together making it impossible to get the PAO at the proper surface area that will dissolve all Said...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B05D5/08
CPCF17D1/17Y10T137/0391
Inventor T·马修N·S·科马莱迪
Owner BAKER HUGHES INC
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