Composition of styrene based copolymer, polymerization method of said composition, and styrene based copolymer obtained from the method
A technology of styrenic and vinyl compounds, applied in the field of styrenic copolymer resin compositions, can solve the problems of insufficient mechanical properties, coloration, low molecular weight, etc., achieve excellent appearance and light resistance, maintain moldability, improve The effect of appearance quality
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Embodiment 1
[0056]90 parts by weight of styrene (SM) and 10 parts by weight of methacrylic acid (MAA) were mixed to prepare a monomer composition. Add 14 parts by weight of ethylbenzene, 4 parts by weight of 2-ethylhexanol, 1 part by weight of diethylene glycol monobutyl ether, 200 ppm malonic acid [(4-methoxyphenyl) in 100 parts by weight of the monomer composition -methylene]dimethyl ester (Hostavin PR-25 manufactured by Clariant), and 100 ppm 2,2-bis(4,4-bis(tert-butylperoxy)cyclohexyl)propane (available from NOF Corporation's Pertetra-A). The reaction mixture thus prepared is then introduced into the first reactor, followed by polymerization. The temperature of the first reactor to which the composition was added was set at 135°C, the temperature of the second reactor was set at 140°C, and the residence time of the reactants was adjusted to give a final conversion of 60%. Next, the resulting reaction mixture was transferred to a continuous devolatilization device, and then the tempe...
Embodiment 2
[0058] A granular copolymer resin was prepared in the same manner as in Example 1, except that 2 parts by weight of 2-ethylhexanol and 3 parts by weight of diethylene glycol monobutyl ether were added as plasticizers.
Embodiment 3
[0060] A granular copolymer resin was prepared in the same manner as in Example 1, except that 1.5 parts by weight of 2-ethylhexanol and 0.5 parts by weight of diethylene glycol monobutyl ether were added as plasticizers.
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