Dental composition, kit of parts and use thereof
一种组合物、化合物的技术,应用在牙科、牙科假体、牙科制剂等方向,能够解决固化组合物和齿腔体壁形成间隙等问题
Active Publication Date: 2013-03-20
3M INNOVATIVE PROPERTIES CO
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Problems solved by technology
In particular, in the field of dentistry, this can cause problems, such as the possible formation of gaps between the curing composition and the tooth cavity walls
Method used
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[0254] Unless otherwise indicated, all parts and percentages are by weight, all water is deionized water, and all molecular weights are weight average molecular weights. Furthermore, all experiments were performed under ambient conditions (23°C; 1013 mbar) unless otherwise stated. Furthermore, almost all method steps are performed under an atmosphere of dry air:
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Abstract
The application relates to a dental composition comprising a) a compound (A) with the following features: only one backbone unit (U) with 6 to 20 carbon atoms, at least 6 carbon atoms thereof forming an aromatic or an aliphatic cyclic moiety, the remaining carbon atoms either being part of substituents pending from the cyclic moiety or being part of bridging groups to spacer units, wherein one or more of the remaining carbon atoms can be replaced by an oxygen atom, the backbone unit not comprising a bisphenol structure and halogen atoms, one or two unit(s) (S) being connected to the backbone unit (U) via an ether linkage, at least one unit (S) comprising a - CH2 - CH2 - CH2 - CH2 - O - CH2 - CH (Q) - OG moiety or a CH2-CH(OG) -CH2-OM moiety or a mixture of these two types of moieties within one unit (S), with G comprising at least one polymerizable moiety and an urethane moiety, the urethane moiety acting as connecting element to unit(s) (S), and M comprising at least one group selected from acroyl, methacroyl, aryl, mixtures and combinations thereof, Q comprising at least one group selected from hydrogen, methyl, phenyl, phenoxymethyl, mixtures and combinations thereof, and with the proviso that onto the backbone unit (U) at least two substituents are attached, each bearing at least one group G, wherein in the case where only one unit (S) is present, the group G not being part of said unit (S) is located in the further substituent pending from unit (U), b) a filler (B) and c) an initiator (C).
Description
technical field [0001] The present invention relates to compositions comprising a hardenable compound comprising a relatively rigid backbone unit, a spacer unit and a unit comprising a polymerizable end group linked to the spacer unit via a carbamate moiety. [0002] The present composition is useful in the field of dentistry, and especially for providing so-called low stress composite filling materials. Background technique [0003] Volume shrinkage of curable compositions during the curing process has long been known. In particular, in the field of dentistry, this can cause problems, such as the possible formation of gaps between the curing composition and the tooth cavity walls. Can lead to infection of the remaining tooth structure. Various efforts have been made to solve this problem. [0004] US 2009 / 0036565 relates to TCD (i.e. tricyclic [5.2.1.0 2,6 ] Dental composites of decane-3 / 4,8 / 9-diyl) derived monomers wherein the flexural strength / shrink tension quotient ...
Claims
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IPC IPC(8): A61K6/09A61K6/083C07C271/16A61K6/893
CPCA61K6/0023C07C2103/66A61K6/083C07C2103/64A61K6/09C07C271/16C07C2603/64C07C2603/66A61K6/893A61K6/30A61K6/887C08L75/16C08L33/00
Inventor A·埃克特M·库布B·海兰德M·克斯特尔K·迪德U·霍艾泽尔G·赖亚C·塔拉克R·黑希特T·卢赫特汉特P·比辛格尔W·施泰格尔
Owner 3M INNOVATIVE PROPERTIES CO
