Method for removing hydrochloric ether contained in underground water and soil mud system through chemical reduction
A technology for chlorinated hydrocarbons and groundwater, which is applied in the field of environmental treatment, can solve the problems of less simultaneous treatment and decreased removal efficiency of chlorinated hydrocarbons, and achieves the effects of simple and easy operation, remarkable treatment effect and wide application
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Embodiment 1
[0029] Add 50g of zero-valent iron (per kg of soil (dry weight)) to the substrate where 1,1,1-trichloroethane pollution concentration is 100mg / kg polluted soil (guarantee water-soil ratio is 5:1), and carry out slowly And fully mechanically stirred, while controlling the pH of the mud system to be 7, the reaction temperature is 20°C, and the reaction time is 24 hours. Sampling and extraction are carried out at 2, 4, 6, 8, 10, 12, 16, 20, and 24 hours respectively. , using a gas chromatograph to analyze the concentration of 1,1,1-trichloroethane, as a result, the removal rate of 1,1,1-trichloroethane treated by the process of the present invention reaches 99.5% in about 24 hours.
Embodiment 2
[0031] Add 200g of zero-valent iron (per kg of soil (dry weight)) to the substrate where the concentration of 1,1,1-trichloroethane is 100 mg / kg of polluted soil (to ensure that the water-to-soil ratio is 5:1), and carry out slowly And fully mechanically stirred, while controlling the pH of the mud system to be 7, the reaction temperature is 20°C, and the reaction time is 24 hours. Sampling and extraction are carried out at 2, 4, 6, 8, 10, 12, 16, 20, and 24 hours respectively. , using a gas chromatograph to analyze the concentration of 1,1,1-trichloroethane, as a result, the removal rate of 1,1,1-trichloroethane treated by the process of the present invention reaches 99.9% in about 12 hours.
Embodiment 3
[0033] In the substrate where 1,1,1-trichloroethane pollution concentration is 500mg / kg polluted soil (guarantee water-to-soil ratio is 5:1), add 50g zero-valent iron (per kg soil (dry weight)), carry out slowly And fully mechanically stirred, while controlling the pH of the mud system to be 7, the reaction temperature is 20°C, and the reaction time is 24 hours. Sampling and extraction are carried out at 2, 4, 6, 8, 10, 12, 16, 20, and 24 hours respectively. , using a gas chromatograph to analyze the concentration of 1,1,1-trichloroethane, as a result, the removal rate of 1,1,1-trichloroethane treated by the process of the present invention reaches 99.5% in about 24 hours.
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