Coating composition and method for forming multilayer coating film
A multi-layer coating film and composition technology, which is applied in coatings, devices for coating liquid on the surface, etc., can solve the problems of insufficient appearance of multi-layer coating films, and achieve excellent concealment, improved concealment, and weather resistance excellent effect
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[0203] Examples and comparative examples are given below to further specifically describe the present invention. However, the present invention is not limited only to these examples. It should be noted that both "parts" and "%" are obtained on a mass basis.
[0204] Production of hydroxyl-containing acrylic resin (I-1)
manufacture example 1
[0206] In a reaction vessel equipped with a thermometer, a thermostat, a stirring device, a reflux condenser, and a dripping device, add 70.7 parts of deionized water and "Aquaron KH-10" (trade name, manufactured by Daiichi Kogyo Pharmaceutical Co., Ltd., emulsifier, effective Ingredient 97%) 0.52 parts, stirred and mixed in a nitrogen flow, and heated to 80°C. Next, 1% of the total amount in the following monomer emulsion and 5 parts of 6% ammonium persulfate aqueous solution were introduced into the reaction container and held at 80° C. for 15 minutes. Then, the remaining monomer emulsion was added dropwise to the reaction vessel kept at the same temperature in 3 hours, and after the dropwise addition was completed, it was matured for 1 hour, and then 40 parts of 5% 2-(dimethylamino)ethanol aqueous solution was slowly was added to the reaction vessel while cooling to 30° C., filtered with 100-mesh nylon cloth, and discharged at the same time to obtain a hydroxyl-containing a...
manufacture example 2
[0209] In a reaction vessel equipped with a thermometer, a thermostat, a stirring device, a reflux condenser, and a dripping device, add 130 parts of deionized water and 0.52 parts of "Aquaron KH-10", stir and mix in a nitrogen stream, and raise the temperature to 80°C . Next, 1% of the total amount in the following monomer emulsion (1) and 5.3 parts of 6% ammonium persulfate aqueous solution were introduced into the reaction container and held at 80° C. for 15 minutes. Then, the remaining monomer emulsion (1) was added dropwise to the reaction container kept at the same temperature over 3 hours, and aged for 1 hour after completion of the dropwise addition. Then add the following monomer emulsion (2) dropwise over 1 hour, and after aging for 1 hour, slowly add 40 parts of 5% dimethylethanolamine aqueous solution to the reaction vessel while cooling to 30°C, and filter with 100-mesh nylon cloth , and discharged at the same time to obtain a hydroxyl group-containing particle w...
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