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A kind of naphtha catalytic reforming method

A technology for catalytic reforming and naphtha, applied in the field of hydrocarbon conversion, can solve the problems of small scale of the first reactor and the like

Active Publication Date: 2016-01-13
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the small scale of the first reactor, the capacity expansion of old devices is often limited by the adhesion of the first reactor catalyst

Method used

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  • A kind of naphtha catalytic reforming method
  • A kind of naphtha catalytic reforming method
  • A kind of naphtha catalytic reforming method

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0027] When the method of the invention is adopted to carry out the continuous reforming reaction of naphtha, the circulating hydrogen from the outlet of the compressor of the continuous reforming device does not enter the first reactor, but all enters the second reactor. The continuous reforming catalyst RC011 produced by Hunan Jianchang Catalyst Co., Ltd. was used, which contained 0.28% by mass of Pt and 0.41% by mass of Sn, and the carrier was γ-alumina. The properties of the refined naphtha used are shown in Table 1, and the reaction conditions and results are shown in Table 2.

example 2

[0029] Adopt the method of the present invention to carry out the naphtha continuous reforming reaction, the circulating hydrogen from the compressor outlet of the continuous reforming unit does not enter the first reactor, and is divided into two streams and enters the second reactor and the fourth reactor respectively, wherein 80% by volume The circulating hydrogen of 20% by volume enters the second reactor, and the circulating hydrogen of 20% by volume enters the fourth reactor. Catalyst used and naphtha are all the same as example 1, and reaction conditions and results are shown in Table 2.

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Abstract

The invention discloses a catalytic reforming method of naphtha. Naphtha is introduced into three or four reforming reactors which are connected with one another in series and are filled with a reforming catalyst; and reforming circulating hydrogen is introduced into the second reactor, or is divided into a plurality of strands, and is respectively introduced into the second reactor and various reactors on the downstream. According to the method, the reforming circulating hydrogen is not introduced into the first reactor, so that the total amount of carbon deposit of the catalyst can be reduced, the service life of the catalyst is prolonged, and the yield of a C5<+> liquid product is increased.

Description

technical field [0001] The invention is a hydrocarbon conversion method, in particular, a naphtha catalytic reforming method. Background technique [0002] The continuous catalytic reforming of naphtha has the characteristics of high liquid yield, high hydrogen production and high yield of aromatics. It has received great attention in the production of high-octane gasoline and aromatics, and will be used in the reforming process development process in the future. play a leading role in. [0003] The continuous reformer includes a reaction unit and a catalyst regeneration unit. Different types of continuous reforming processes employ different types of catalyst regeneration units. At present, most continuous reforming units in the world use four reactors, and a small number of reforming units use three reactors. The process of the reaction unit of the conventional continuous reforming unit is generally as follows: after the refined naphtha from the reforming pre-hydrogenat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G35/09
Inventor 王杰广马爱增任坚强张新宽
Owner CHINA PETROLEUM & CHEM CORP
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