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Vinyl chloride resin composition for powder molding, vinyl chloride resin molded article and laminate

A technology of vinyl chloride resin and composition, which is applied in the direction of synthetic resin layered products, coatings, layered products, etc., and can solve the problems of reduced heat aging resistance of skin materials, easy volatility, and inability to prevent long-term skin transfer of tertiary amines, etc.

Active Publication Date: 2015-07-29
ZEON CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the above-mentioned amine scavenger is volatile, it cannot prevent the transfer of tertiary amines to the skin formed by vinyl chloride resin for a long time, so the discoloration of the skin material caused by the above chemical reaction cannot be prevented for a long time, and the heat aging resistance of the skin material is reduced.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~10 and comparative example 1~11

[0076] Mix the ingredients shown in Table 1 and Table 2 except the plasticizer and release agent in a Henschel mixer, and add the plasticizer when the temperature of the mixture rises to 80°C. It is completely dry (it is called the state where the plasticizer is absorbed by the vinyl chloride resin particles and the above mixture becomes loose.), and then when the composition is cooled to below 70°C, add vinyl chloride resin particles as a release agent to prepare a powder Vinyl chloride resin composition for molding. Then, sprinkle the vinyl chloride resin composition for powder molding into a textured mold heated to 250°C, place it for 13 seconds to melt, shake off the remaining composition, and place it in an oven set at 200°C Then, after 60 seconds, the mold was cooled with cooling water, and when the mold temperature was cooled to 40° C., a vinyl chloride resin molded sheet of 205 mm×298 mm×1 mm was released from the mold. The obtained vinyl chloride resin molded sheet w...

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Abstract

This vinyl chloride resin composition for powder molding contains (a) 100 parts by mass of vinyl chloride resin particles having an average degree of polymerization of 2300-4100 and (b) 100-200 parts by mass of a plasticizer containing a trimellitate plasticizer and / or a pyromellitate plasticizer.

Description

technical field [0001] The present invention relates to a vinyl chloride resin composition for powder molding, which provides a skin material having long-term heat aging resistance even if a foamed polyurethane layer is laminated; powder slush molding of the above vinyl chloride resin composition for powder molding The resulting vinyl chloride resin molded body; a laminate provided with the above-mentioned vinyl chloride resin molded body and foamed polyurethane molded body. Background technique [0002] An automobile instrument panel has a structure in which a foamed polyurethane layer is provided between a skin made of vinyl chloride resin and a base material. The skin formed by vinyl chloride resin changes color over time, and its heat aging resistance decreases. One of the causes of this discoloration is the transfer of tertiary amine used as a catalyst when forming the foamed polyurethane layer to the skin formed by vinyl chloride resin. chemical reaction. In order to...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06B29C41/18B32B27/30B32B27/40B60K37/00B60R13/02C08K3/26C08K3/34C08K5/07C08K5/09C08K5/12C08L63/00
CPCC08K5/098C08L63/00B29C41/18C08K5/12C08K3/26B60K37/00C08L27/06C08L2205/025C08L2201/08C08L91/00C08K13/02C08K3/34C08K3/04Y10T428/249992B60K37/20B32B5/18B32B27/065B32B27/40B32B27/304B32B2250/02B32B2250/24
Inventor 岩堀孝久北川祐也
Owner ZEON CORP