Method for preparing conducting polymer pyroelectric nano film

A technology of conductive polymers and nano-films, applied in coatings and other directions, can solve problems such as low energy factor, difficulty in obtaining high-performance thermoelectric materials, poor stability, etc., achieve high pyroelectric coefficient, good application prospects, high temperature thermal good stability effect

Inactive Publication Date: 2015-11-25
UNIV OF ELECTRONICS SCI & TECH OF CHINA
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, conductive polymers still have the following problems as thermoelectric materials: (1) Poor stability
Usually conductive polymer thermoelectric materials have better conductivity after doping, but as the conductivity increases, the Seebeck coefficient decreases significantly, so the obtained energy factor is low, and it is difficult to obtain high performance. thermoelectric materials

Method used

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  • Method for preparing conducting polymer pyroelectric nano film
  • Method for preparing conducting polymer pyroelectric nano film

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0061] ① Dissolve polysuccinic acid bis-(2-ethylhexyl) sodium sulfonate in N,N dimethylformamide solvent, the concentration of polysuccinic acid bis-(2-ethylhexyl) sodium sulfonate is 2.5 moles / L to form a nanowire stencil solution for monomer polymerization;

[0062] ② Dissolving 3,4-ethylenedioxythiophene in n-butanol solvent, the concentration of 3,4-ethylenedioxythiophene is 1 mole / liter, forming a monomer solution;

[0063] ③After mixing the solutions formed by ① and ②, add an aqueous solution of iron toluenesulfonate to initiate polymerization, and the concentration of toluenesulfonic acid is 2 mol / liter, thereby obtaining ultra-long nanowires of poly-3,4-ethylenedioxythiophene solution;

[0064] ④ Mix poly-3,4-ethylenedioxythiophene nanowire solution with chloroform solvent (volume ratio 4:1) to obtain conductive polymer nanowire solution suitable for LB film spreading;

[0065] ⑤ Use a micro-injector to extract 800 μl of the conductive polymer nanowire solution obta...

example 2

[0070] In Example 2, the conductive polymer monomer is thiophene, and the rest of the materials and manufacturing process are similar to those in Embodiment 1, so as to obtain a polythiophene nanowire pyroelectric film.

example 3

[0072] In Example 3, the conductive polymer monomer is α-chloromethylthiophene, and the rest of the materials and manufacturing process are similar to those in Embodiment 1, so as to obtain poly-α-chloromethylthiophene nanowire pyroelectric film.

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Abstract

The embodiment of the invention discloses a method for preparing a conducting polymer pyroelectric nano film. The method comprises the steps of preparing a conducting polymer nano wire by adopting a template process; then preparing a conducting polymer nano wire film by adopting an LB film process; and finally, doping and reducing the nano wire film by adopting a chemical process to obtain the conducting polymer pyroelectric nano film structure. The conducting polymer pyroelectric nano film prepared by adopting the method disclosed by the invention has the advantages of high pyroelectric coefficient, high thermal conductance and good stability, and has wide application in micro/nano energy collection and energy storage devices.

Description

technical field [0001] The invention relates to the technical field of conductive polymer pyroelectric materials, in particular to a method for manufacturing a flexible conductive polymer pyroelectric nano film with high pyroelectric coefficient. Background technique [0002] With the approaching of the energy crisis, the research of conductive polymer thermoelectric materials has attracted more and more attention. Compared with inorganic thermoelectric materials, the thermoelectric properties of the reported conductive polymer thermoelectric materials are average, and the thermal stability is relatively poor, so the development of conductive polymer thermoelectric materials is relatively slow. However, due to the outstanding advantages of abundant resources, low price, easy synthesis, easy processing, and low thermal conductivity, conductive polymer materials are considered to be one of the most promising thermoelectric materials. In recent years, the thermoelectric prop...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J7/00C08J7/14C08J5/18C08L65/00C08G61/12C08J7/04C08L69/00C08L83/04
Inventor 杨亚杰彭田军杨文耀徐建华蒋亚东
Owner UNIV OF ELECTRONICS SCI & TECH OF CHINA
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