41results about How to "High pyroelectric coefficient" patented technology

The invention which relates to an FE-AFE phase change pyroelectric ceramic material belongs to the field of pyroelectric ceramic. The invention discloses the FE-AFE phase change pyroelectric ceramic material, a pyroelectric ceramic element and preparation methods of the material and the element. Chemical components of the ceramic material accord with a general chemical formula of (Pb1-3x / 2Lax)(ZryTizSn1-y-z)O3, wherein x is more than 0 and equal to or less than 0.025, y is from 0.38 to 0.46, and z is from 0.14 to 0.18; and the ceramic material is in a ferroelectric phase at room temperature and can generate an FE-AFE phase change with the temperature change with or without an extra electric field. The pyroelectric ceramic element has a large polarized change with the FE-AFE phase change after being polarized or under the effect of a direct current bias, so a large pyroelectric response is obtained, a pyroelectric coefficient is 2-4 times more than traditional pyroelectric coefficients, and heat stagnation substantially does not exist, so the pyroelectric ceramic element can be used in the uncooled infrared detection technology and the fields of heat-electrical energy transformation and the like.

The invention discloses a composite pyroelectric material and a preparation method thereof as well as a method used in the preparation of a silica-based thick film. The material is a composite material of polyvinylidene fluoride and Pb1+x(Sc0.5Ta0.5)O3 nano ceramic powder, wherein x is more than or equal to 0.05 and less than or equal to 0.1; and the volume percent of the nano ceramic powder is 30 to 70 percent. The preparation method of the composite pyroelectric material and the silica-based thick film thereof comprises the following steps: (1) scandium lead tantanate precursor sol is prepared and scandium lead tantanate nano power is prepared by means of the sol; (2) PVDF solution and scandium lead tantanate PVDF composite slurry are prepared; (3) after the pretreatment of silicone substrate is completed, a thermal insulation layer and a bottom electrode are deposited; (4) the spin coating and the deposition of a composite pyroelectric thick film are completed; and (5) an upper electrode is deposited and polarized. The composite pyroelectric material, which has the advantages of both organic pyroelectric material and inorganic pyroelectric material, has a small dielectric constant, low thermal conductivity and very high voltage response optimal value; meanwhile, because film-forming temperature is extremely low, the material is suitable to be used in semiconductor integration process; moreover, the thickness of the composite pyroelectric thick film can be controlled within 5 micron and 20 micron, which ensures higher film-forming efficiency.

The invention relates to a PZT (lead zirconate titanate)-based antiferroelectric ceramic material with low curie point TC and a high bidirectional-adjustable dielectric electric field and a preparation method thereof and belongs to the technical fields of electronic materials and devices. The chemical general formula of the PZT-based antiferroelectric ceramic material with bidirectional adjustability of a dielectric electric field is (Pb[0.99-x-y]BaxLay)(Zr0.51Sn 0.39Ti0.10)O3, wherein x is larger than 0 and less than or equal to 0.20, and y is larger than 0 and less than or equal to 0.06. The PZT-based antiferroelectric ceramic material with dielectric bidirectional adjustability has high dielectric coefficient and low dielectric loss under a certain bias voltage in the vicinity of low curie point TC, and the dielectric coefficient is increased and then decreased along with the increase of the bias voltage; the PZT-based antiferroelectric ceramic material has bidirectional dielectric adjustability, simultaneously has high pyroelectric coefficient and pyroelectric current, and can be widely used in the fields of microelectronics, computers, capacitors, sensors, aerospace technologies and the like.

The invention discloses an antiferroelectric thin film with adjustable working temperature range and large pyroelectric coefficient, its preparation method and application. The antiferroelectric thin film (Pb, La or Nb) (Zr, Sn, Ti) O of the present invention as pyroelectric material, it adopts sol-gel method to prepare, and the solute of precursor solution is lead acetate, lanthanum acetate La Or niobium ethoxide, tin acetate, zirconium isopropoxide and titanium isopropoxide, the solvent is glacial acetic acid, ethylene glycol ether, acetylacetone and water, the final concentration of the precursor solution is controlled between 0.2-0.4M, the substrate is LaNiO3 / Pt / Ti / SiO2 / Si and Pt / Ti / SiO2 / Si. The antiferroelectric thin film of the invention has high pyroelectric current and adjustable temperature, and can be used in infrared pyroelectric detectors, smart devices and systems.

The embodiment of the present invention discloses a method for manufacturing a conductive polymer pyroelectric nano film, which includes: preparing a conductive polymer nanowire film by a template method, then preparing a conductive polymer nanowire film by a LB film method, and finally using a chemical method to prepare a conductive polymer nanowire film. The nanowire film is doped and reduced to obtain a conductive polymer pyroelectric nano film structure. The conductive polymer pyroelectric nano film prepared by the invention has the advantages of high pyroelectric coefficient, low heat conduction and good stability, and has wide application in micro / nano energy collection and energy storage devices.

The invention discloses a multielement composite pyroelectric ceramic material and a preparation method thereof. The chemical general formula of the material is xPb(Me1 / 3Nb2 / 3)O3-yPb(Fe1 / 2Nb1 / 2)O3-zPb(Zr0.9Ti0.1)O3-mMe', wherein Me is one of Mn or Zn; x, y and z are respectively a mole coefficient, x is greater than or equal to 0.01 and less than or equal to 0.07, y is greater than or equal to 0.01 and less than or equal to 0.07, z is greater than or equal to 0.9 and less than or equal to 0.92, and x + y + z = 1; and Me' is a modifying metal element, m is a mole coefficient, and m is greater than or equal to 0 mol % and less than or equal to 5 mol %. The multielement composite pyroelectric ceramic material provided by the invention has a high pyroelectric coefficient, proper dielectric properties and a low dielectric loss, and the electrical properties can be adjusted, therefore, the multielement composite pyroelectric ceramic material has a good prospect in devices such as pyroelectric detectors and the like.

The invention relates to a pyroelectric ceramic material for a passive pyroelectric infrared sensor, the chemical element composition of which is: (Pb1-x-yLaxSry) (Mn1 / 3Nb2 / 3)z(Zr0.94Ti0.06)1-zO3+ φat%A; where: 0.002≤x≤0.1, 0.01≤y≤0.1, 0.01≤z≤0.1; where, φ=0 or 2.8≤φ≤5.5, said A is a mixture of B2O3 and Cr2O3, the two The molar ratio is 1:1. The pyroelectric ceramic material of the present invention has a low sintering temperature and a wide sintering temperature range, and because of the low phase transition temperature, small spontaneous polarization, low dielectric constant and dielectric loss, the passive infrared pyroelectric sensor produced has noise Low value, high sensitivity, long detection distance; suitable for making sensors such as pyroelectric passive infrared sensors and uncooled focal plane infrared sensors.

The invention discloses a preparation method of a nano tourmaline modified dust removal filter material, which belongs to the technical field of high-temperature smoke dust removal. The preparation method comprises the following steps: carrying out heat treatment for nano tourmaline powder; weighing sodium hexametaphosphate and sodium polyacrylate, and mixing the sodium hexametaphosphate and sodium polyacrylate with water; weighing nano tourmaline powder, adding water, and mixing with PTFE emulsion; adding the sodium hexametaphosphate and sodium polyacrylate into a mixed solution of the nano tourmaline powder and PTFE emulsion, and obtaining a nano tourmaline treatment solution; soaking a filter material test sample in the nano tourmaline treatment solution, and obtaining a nano tourmaline filter material; and polarizing the nano tourmaline filter material by virtue of electrets, and obtaining the nano tourmaline modified dust removal filter material. By adopting the preparation method, not only is electrets performance high, small dust can be trapped, the dust filter efficiency can be improved, the dust removing rate can be increased, and the equipment resistance is reduced.

The invention discloses a method for preparing a porous barium strontium titanate field pyroelectric ceramic, comprising the following steps: firstly, mixing raw materials according to a stoichiometric ratio of respective chemical formula; pre-sintering the mixture at 800-1200 DEG C for 1-6 hours to obtain pre-sintered ceramic powder; then adding an organic substance pore-forming agent, mixing uniformly, tabletting and forming; heating again to remove organic substances; sintering, grinding, cleaning, adding an electrode and sintering the electrode. The porous BST field pyroelectric ceramic of the invention has the advantages of high pyroelectric coefficient, low dielectric loss, proper dielectric constant and excellent comprehensive pyroelectric property, and meets the requirements for manufacturing pyroelectric infrared detectors.

The invention relate to a method for preparing high-performance BST (barium strontium titanate) pyroelectric ceramics by adopting a post-annealing process. According to the method, BST ceramics obtained through sintering is subjected to annealing at the oxygen atmosphere, the annealing temperature ranges from 800 DEG C to 1,250 DEG C, the annealing time ranges from 2 hours to 5 hours, and then the high-performance BST pyroelectric ceramics can be prepared. According to the method for preparing the high-performance BST pyroelectric ceramics by adopting the post-annealing process, the annealing treatment is performed after the BST pyroelectric ceramics is obtained through sintering, and the high-performance BST pyroelectric ceramics can be prepared; the dielectric constant is high and can be higher than 9,500; the pyroelectric coefficient is high and can be higher than 18*10<-8>C / cm<2>K; and further, a sample is high in purity and performance and good in uniformity, manufacturing requirements of an uncooled infrared focal plane device can be met, and the problem that the BST ceramics cannot be sintered to high density is effectively solved.