A method for manufacturing conductive polymer pyroelectric nano film

A technology of conductive polymers and nano-films, applied in coatings and other directions, can solve problems such as poor stability, difficulty in obtaining high-performance thermoelectric materials, and low energy factors, and achieve good high-temperature thermal stability, good application prospects, and high heat The effect of discharge coefficient

Inactive Publication Date: 2018-02-23
UNIV OF ELECTRONICS SCI & TECH OF CHINA
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, conductive polymers still have the following problems as thermoelectric materials: (1) Poor stability
Usually conductive polymer thermoelectric materials have better conductivity after doping, but as the conductivity increases, the Seebeck coefficient decreases significantly, so the obtained energy factor is low, and it is difficult to obtain high performance. thermoelectric materials

Method used

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  • A method for manufacturing conductive polymer pyroelectric nano film
  • A method for manufacturing conductive polymer pyroelectric nano film

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0061] ① Dissolve polysuccinic acid bis-(2-ethylhexyl) sodium sulfonate in N, N dimethylformamide solvent, the concentration of polysuccinic acid bis-(2-ethylhexyl) sodium sulfonate is 2.5 moles / L to form a nanowire stencil solution for monomer polymerization;

[0062] ② Dissolving 3,4-ethylenedioxythiophene in n-butanol solvent, the concentration of 3,4-ethylenedioxythiophene is 1 mole / liter, forming a monomer solution;

[0063] ③After mixing the solutions formed by ① and ②, add an aqueous solution of iron toluenesulfonate to initiate polymerization, and the concentration of toluenesulfonic acid is 2 mol / liter, thereby obtaining ultra-long nanowires of poly-3,4-ethylenedioxythiophene solution;

[0064] ④ Mix poly-3,4-ethylenedioxythiophene nanowire solution with chloroform solvent (volume ratio 4:1) to obtain conductive polymer nanowire solution suitable for LB film spreading;

[0065] ⑤ Use a micro-injector to extract 800 μl of the conductive polymer nanowire solution obt...

example 2

[0070] In Example 2, the conductive polymer monomer is thiophene, and the rest of the materials and manufacturing process are similar to those in Embodiment 1, so as to obtain a polythiophene nanowire pyroelectric film.

example 3

[0072] In Example 3, the conductive polymer monomer is α-chloromethylthiophene, and the rest of the materials and manufacturing process are similar to those in Embodiment 1, so as to obtain poly-α-chloromethylthiophene nanowire pyroelectric film.

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Abstract

The embodiment of the present invention discloses a method for manufacturing a conductive polymer pyroelectric nano film, which includes: preparing a conductive polymer nanowire film by a template method, then preparing a conductive polymer nanowire film by a LB film method, and finally using a chemical method to prepare a conductive polymer nanowire film. The nanowire film is doped and reduced to obtain a conductive polymer pyroelectric nano film structure. The conductive polymer pyroelectric nano film prepared by the invention has the advantages of high pyroelectric coefficient, low heat conduction and good stability, and has wide application in micro / nano energy collection and energy storage devices.

Description

technical field [0001] The invention relates to the technical field of conductive polymer pyroelectric materials, in particular to a method for manufacturing a flexible conductive polymer pyroelectric nano film with high pyroelectric coefficient. Background technique [0002] With the approaching of the energy crisis, research on conductive polymer thermoelectric materials has attracted more and more attention. Compared with inorganic thermoelectric materials, the thermoelectric properties of the reported conductive polymer thermoelectric materials are average, and the thermal stability is relatively poor, so the development of conductive polymer thermoelectric materials is relatively slow. However, due to the outstanding advantages of abundant resources, low price, easy synthesis, easy processing, and low thermal conductivity, conductive polymer materials are considered to be one of the most promising thermoelectric materials. In recent years, the thermoelectric properties...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J7/00C08J7/14C08J5/18C08L65/00C08G61/12C08J7/04C08L69/00C08L83/04
Inventor 杨亚杰彭田军杨文耀徐建华蒋亚东
Owner UNIV OF ELECTRONICS SCI & TECH OF CHINA
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