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Three-dimensional Cu (II) coordination polymer and preparation method thereof and one-dimensional Cu (I) coordination polymer prepared from three-dimensional Cu (II) coordination polymer and a preparation method thereof

A coordination polymer and three-dimensional technology, applied in chemical instruments and methods, luminescent materials, etc., can solve the problems of poor monochromaticity, high raw material cost of yellow fluorescent materials, cumbersome synthesis methods, etc., and achieve low synthesis cost and green synthesis cost The effect of environmental protection and simple preparation method

Inactive Publication Date: 2016-05-04
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The purpose of the present invention is to solve the problems of cumbersome synthetic methods for preparing Cu(I) coordination polymers, high raw material cost of yellow fluorescent materials, poor monochromaticity and short optical life of the prepared yellow fluorescent materials, and provide three-dimensional Cu (II) Coordination polymer and preparation method thereof, and one-dimensional Cu(I) coordination polymer and method prepared therefrom

Method used

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  • Three-dimensional Cu (II) coordination polymer and preparation method thereof and one-dimensional Cu (I) coordination polymer prepared from three-dimensional Cu (II) coordination polymer and a preparation method thereof
  • Three-dimensional Cu (II) coordination polymer and preparation method thereof and one-dimensional Cu (I) coordination polymer prepared from three-dimensional Cu (II) coordination polymer and a preparation method thereof
  • Three-dimensional Cu (II) coordination polymer and preparation method thereof and one-dimensional Cu (I) coordination polymer prepared from three-dimensional Cu (II) coordination polymer and a preparation method thereof

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specific Embodiment approach 1

[0046] Specific implementation mode one: the present implementation mode is a three-dimensional Cu(II) coordination polymer whose molecular formula is [Cu 2 (C 25 h 15 N 2 o 7 )·H 2 O] n , whose structure is:

[0047]

[0048] Wherein, said n is a positive integer; said O1, O1A, O2, O2A, O3, O3A, O4, O4A, O6, O6A, O8 and O8A are in the basic structural unit of three-dimensional Cu(II) coordination polymer The occupancy rate in all is 0.5; The occupancy rate of described O5, O5A and O5B in the basic structural unit of three-dimensional Cu(II) coordination polymer is all 1 / 3; Described O7 is in three-dimensional Cu(II) The occupancy of the basic structural unit of the coordination polymer is 1; the occupancy of the Cu1 in the basic structural unit of the three-dimensional Cu (II) coordination polymer is 1; the Cu2 and Cu3 are in the three-dimensional Cu ( II) The occupancy ratios of the basic structural units of the coordination polymer are all 0.5; the occupancy ratio...

specific Embodiment approach 2

[0050] Specific embodiment 2: The difference between this embodiment and specific embodiment 1 is that the basic structural unit of the three-dimensional Cu(II) coordination polymer contains three Cu 2+ ion;

[0051] Among them, the three Cu 2+ The ions are: central metal Cu1, central metal Cu2 and central metal Cu3; their coordination and bonding methods are as follows:

[0052] Central metal Cu1 and a nitrogen atom N1 in the 4,4'-bipyridine ligand, and a carboxyl group at the 3'-position in a 3-(2',3'-dicarboxyphenoxy)benzoic acid ligand O1 in, and O3 and O4 in the carboxyl group at the 2'-position in the 3-(2',3'-dicarboxyphenoxy)benzoic acid ligand, and 3-(2',3'-di Carboxyphenoxy) O6 in the carboxyl group at the 3-position in the benzoic acid ligand and O8 on the coordinated water molecule coordinate to form a bond;

[0053] Central metal Cu2 and O1 in the carboxyl group at the 3'-position, O5 in the carboxyl group at the 3-position, and another 3 -(2',3'-dicarboxyphen...

specific Embodiment approach 3

[0055] Specific embodiment three: the difference between this embodiment and specific embodiment one or two is: the three Cu 2+ The coordination numbers of the ions are 6, 6, and 4, respectively, and the spatial configurations presented are octahedron, octahedron, and tetrahedron, respectively. Others are the same as those in Embodiment 1 or 2.

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Abstract

The invention discloses a three-dimensional Cu (II) coordination polymer and a preparation method thereof and a one-dimensional Cu (I) coordination polymer prepared from the three-dimensional Cu (II) coordination polymer and a preparation method thereof, and aims to solve the problems of complicated synthesis method of a Cu (I) coordination polymer and high raw material cost of a yellow fluorescent material in the prior art. The molecular formula of the three-dimensional Cu (II) coordination polymer is [Cu2 (C25H15N2O7).H2O] n; and the preparation method is as follows: 4,4'-bipyridine, a 3-(2 ', 3'-dicarboxy phenoxy) benzoate ligand and cuprous iodide are used for preparation; and the molecular formula of the one-dimensional Cu (I) coordination polymer is [Cu (C25H17N2O7)] 2n; and the preparation method is as follows: the three-dimensional Cu (II) coordination polymer is used for preparation. The three-dimensional Cu (II) coordination polymer can be obtained.

Description

technical field [0001] The invention relates to a preparation of Cu(II) coordination polymer and its preparation method, as well as Cu(I) coordination polymer prepared by using it and the method. Background technique [0002] Metal-organic coordination polymers have attracted widespread attention due to their potential applications in many fields such as luminescence, gas storage and catalysis. Due to the application potential of SCSC reaction in the field of material science, more and more people pay attention to the research of SCSC reaction. The reason why people are becoming more and more interested in studying SCSC reactions is that they can analyze and study the solid-state reaction mechanism. Through the method of single crystal diffraction, people can more directly observe the changes in the crystal structure during the reaction process. Unlike other solid-state reactions, single crystals maintain their integrity, including shape and transparency, during crystal tra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G83/00C09K11/06
CPCC08G83/008C09K11/06C09K2211/1425C09K2211/1466C09K2211/188
Inventor 范瑞清宋阳刘志威谭才图王学涛杨玉林
Owner HARBIN INST OF TECH
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