The invention discloses a method for preparing high-purity
vanadium pentoxide by low-temperature chlorination of high-
calcium and high-
phosphorus vanadium slag. The method includes the six processes of (1) an oxidation
granulation process, (2) a low-temperature chlorination process, (3) a dust collection and
elution process, (4) a rectification and purification process, (5) an oxidation powderingprocess, and (6) a
tailings oxidation process. In this method, an additive is added in the oxidation
granulation process, so that
calcium in the
vanadium slag is converted into a
silicate phase or analuminosilicate phase, and the loss of flow caused by a large amount of
calcium chlorination is avoided. In the low-temperature chlorination process,
carbon monoxide is used as a
carbon source to decrease the chlorination temperature and prevent the loss of flow caused by the melting of calcium and
magnesium chlorides. In the oxidation powdering process and the
tailings oxidation process, the recycling of
chlorine gas is realized by blowing
oxygen-enriched air. The method for preparing high-purity vanadium
pentoxide by low-temperature chlorination of high-calcium and high-
phosphorus vanadium
slag is suitable for the high-calcium and high-
phosphorus vanadium slag and has the advantages of being good in selectivity, low in
reaction temperature, having no loss of flow, being environment-friendly, and high in added value of products.